Lanthanide-Containing Photoluminescent Materials: From Hybrid Hydrogel to Inorganic Nanotubes
文献类型：期刊论文
| 作者 | Qiao, Yan; Lin, Yiyang; Zhang, Shaofei; Huang, Jianbin |
| 刊名 | CHEMISTRY-A EUROPEAN JOURNAL
 |
| 出版日期 | 2011-04-01 |
| 卷号 | 17期号:18页码:5180-5187 |
| 关键词 | Hydrogel Lanthanide Nanotubes Photoluminescence Self-assembly |
| ISSN号 | 0947-6539 |
| DOI | 10.1002/chem.201003255 |
| 英文摘要 | Functional photoluminescent materials are emerging as a fascinating this work, luminescent organic-in-organic hybrid hydrogels are facilely designed through supramolecular self-assembly of sodium cholate, and lanthanide ions such as Eu3+, Tb3+, and Eu3+/Tb3+. Fluorescence microscopy and TEM visualization demonstrates the existence of spontaneously self-assembled nanofibers and 3D networks in hybrid hydrogel. Photoluminescence enhancement of lanthanide ions is realized through coordination with cholate and co-assembly into 1D nanofibers, which can successfully shield the Eu3+ from being quenched by water. The photoluminescence emission intensity of a hybrid hydrogel exhibits strong dependence on europium/cholate molar ratio, with maximum emission appearing at a stoichiometry of 1:3. Further-more, the emission color of a lanthanide-cholate hydrogel can be tuned by utilizing different lanthanide ions or co-doping ions. Moreover, photoluminescent lanthanide oxysulfide inorganic nanotubes are synthesized by means of a self-templating approach based on lanthanide-cholate supramolecular hydrogels. To the best of our knowledge, this is the first time that the lanthanide oxysulfide inorganic nanotubes are prepared in solution under mild conditions. |
| 语种 | 英语 |
| WOS记录号 | WOS:000290213100030 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/72657]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Huang, Jianbin |
| 作者单位 | Peking Univ, Coll Chem & Mol Engn, State Key Lab Struct Chem Unstable & Stable Speci, BNLMS, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qiao, Yan,Lin, Yiyang,Zhang, Shaofei,et al. Lanthanide-Containing Photoluminescent Materials: From Hybrid Hydrogel to Inorganic Nanotubes[J]. CHEMISTRY-A EUROPEAN JOURNAL,2011,17(18):5180-5187. |
| APA | Qiao, Yan,Lin, Yiyang,Zhang, Shaofei,&Huang, Jianbin.(2011).Lanthanide-Containing Photoluminescent Materials: From Hybrid Hydrogel to Inorganic Nanotubes.CHEMISTRY-A EUROPEAN JOURNAL,17(18),5180-5187. |
| MLA | Qiao, Yan,et al."Lanthanide-Containing Photoluminescent Materials: From Hybrid Hydrogel to Inorganic Nanotubes".CHEMISTRY-A EUROPEAN JOURNAL 17.18(2011):5180-5187. |
入库方式： OAI收割
来源：化学研究所
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