Hydrocracking of Anthracene to Ethyl Biphenyl Promoted by Coupling Supercritical Water and Cracking Catalysts
文献类型：期刊论文
| 作者 | Fan, Honglei; Han, Buxing; Jiang, Tao; Guo, Jin; Wang, Qian; Cheng, Yan; Wu, Suxiang |
| 刊名 | CHEMCATCHEM
 |
| 出版日期 | 2011-09-01 |
| 卷号 | 3期号:9页码:1474-1479 |
| 关键词 | Anthracene Ethyl Biphenyl Hydrocracking Supercritical Water |
| ISSN号 | 1867-3880 |
| DOI | 10.1002/cctc.201100142 |
| 英文摘要 | Efficient conversion of polynuclear aromatic hydrocarbons (PAHs) into liquid fuels is crucial for the hydrocracking processes of heavy oils. In this work, we found that the hydrocracking of anthracene catalyzed by NiFe/HZSM-5 could produce ethyl biphenyl (EB), which realizes high efficiency of hydrocracking of anthracene analogous to its central-ring hydrocracking. More interestingly, addition of water could increase the yield of EB significantly, and the yield of EB could be as high as 34%. A pathway for hydrocracking of anthracene to EB and the mechanism for water to enhance the yield of EB are proposed on the basis of control experiments. Furthermore, our work demonstrated that water could also increase the liquid yields and reduce the gaseous yields in the hydrocracking of the Daqing residue oil in the same reaction system. This work not only provides new chemical knowledge on hydrocracking of PAHs, but also provides very important information for improving the hydrocracking processes of heavy oils to obtain more liquid fuels with less hydrogen consumption. |
| 语种 | 英语 |
| WOS记录号 | WOS:000295228400016 |
| 出版者 | WILEY-BLACKWELL |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/72753]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Han, Buxing |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing 100090, Peoples R China |
| 推荐引用方式 GB/T 7714 | Fan, Honglei,Han, Buxing,Jiang, Tao,et al. Hydrocracking of Anthracene to Ethyl Biphenyl Promoted by Coupling Supercritical Water and Cracking Catalysts[J]. CHEMCATCHEM,2011,3(9):1474-1479. |
| APA | Fan, Honglei.,Han, Buxing.,Jiang, Tao.,Guo, Jin.,Wang, Qian.,...&Wu, Suxiang.(2011).Hydrocracking of Anthracene to Ethyl Biphenyl Promoted by Coupling Supercritical Water and Cracking Catalysts.CHEMCATCHEM,3(9),1474-1479. |
| MLA | Fan, Honglei,et al."Hydrocracking of Anthracene to Ethyl Biphenyl Promoted by Coupling Supercritical Water and Cracking Catalysts".CHEMCATCHEM 3.9(2011):1474-1479. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。