Syntheses and crystal structures of two new aluminoborates with helical channels
文献类型:期刊论文
作者 | Wang, Guo-Ming1; Wang, Pei1; Li, Zeng-Xin1; Huang, Hai-Lan1; Wang, Ying-Xia2; Lin, Jian-Hua2 |
刊名 | SOLID STATE SCIENCES
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出版日期 | 2011-08-01 |
卷号 | 13期号:8页码:1567-1572 |
关键词 | Borate Aluminoborate Template Hydrothermal Reaction Porous Material |
ISSN号 | 1293-2558 |
DOI | 10.1016/j.solidstatesciences.2011.05.023 |
英文摘要 | Two new aluminoborates, K-2[AlB5O10]center dot(H2O)(4) (1) and [C5H16H2][AlB5O10] (2), have been synthesized under hydrothermal conditions and characterized by elemental analysis, IR, TG analysis, powder and single-crystal X-ray diffractions. Both of the compounds are monoclinic with the lattice constants a = 6.2410(2) angstrom, b = 13.7188(5) angstrom, c = 6.9301(4) angstrom, beta = 95.365(3)degrees and V = 590.75(4) angstrom(3) in the space group P2(1) for 1 and a = 9.0802(3) angstrom, b = 11.1131(2) angstrom, c = 7.9230(5) angstrom, beta = 117.745(3)degrees and V = 707.58(5) in the space group C-2 for 2. These two structures share a similar three-dimensional framework constructed by AlO4 tetrahedra and B5O10 clusters, containing 6, 8-MR helical channels and odd 11-MR channels, in which the guest templates and H2O molecules are located. (C) 2011 Elsevier Masson SAS. All rights reserved. |
语种 | 英语 |
WOS记录号 | WOS:000294520000020 |
出版者 | ELSEVIER SCIENCE BV |
源URL | [http://ir.iccas.ac.cn/handle/121111/72763] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Wang, Guo-Ming |
作者单位 | 1.Qingdao Univ, Teachers Coll, Coll Chem Chem Engn & Environm, Qingdao 266071, Shandong, Peoples R China 2.Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, Guo-Ming,Wang, Pei,Li, Zeng-Xin,et al. Syntheses and crystal structures of two new aluminoborates with helical channels[J]. SOLID STATE SCIENCES,2011,13(8):1567-1572. |
APA | Wang, Guo-Ming,Wang, Pei,Li, Zeng-Xin,Huang, Hai-Lan,Wang, Ying-Xia,&Lin, Jian-Hua.(2011).Syntheses and crystal structures of two new aluminoborates with helical channels.SOLID STATE SCIENCES,13(8),1567-1572. |
MLA | Wang, Guo-Ming,et al."Syntheses and crystal structures of two new aluminoborates with helical channels".SOLID STATE SCIENCES 13.8(2011):1567-1572. |
入库方式: OAI收割
来源:化学研究所
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