A new fluorescent chemosensor for fluoride anion based on a pyrrole-isoxazole derivative
文献类型：期刊论文
| 作者 | Yang, Zhipei1; Zhang, Kai1; Gong, Fangbin1; Li, Shayu1; Chen, Jun1; Ma, Jin Shi1; Sobenina, Lyubov N.2; Mikhaleva, Albina I.2; Yang, Guoqiang1; Trofimov, Boris A.2 |
| 刊名 | BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | 2011-01-12 |
| 卷号 | 7页码:46-52 |
| 关键词 | Deprotonation Fluorescent Chemosensor Fluoride Anion Recognition |
| ISSN号 | 1860-5397 |
| DOI | 10.3762/bjoc.7.8 |
| 英文摘要 | Molecules containing polarized NH fragments that behave as anion-binding motifs are widely used as receptors for recognition and sensing purposes in aprotic solvents. We present here a new example of a receptor, 3-amino-5-(4,5,6,7-tetrahydro-1H-indol-2yl) isoxazole-4-carboxamide (receptor 1), which contains pyrrole, amide and amino subunits. This receptor shows both changes in its UV-vis absorption and fluorescence emission spectra upon the addition of F-, resulting in highly selectivity for fluoride detection over other anions, such as Cl-, Br-, I-, HSO4-, H2PO4 - and AcO- in CH3CN. H-1 NMR titration, time- dependent density functional theory (TDDFT) calculations and other experiments confirm that the sensing process is brought about by deprotonation of the pyrrole-NH in receptor 1. |
| 语种 | 英语 |
| WOS记录号 | WOS:000286147000001 |
| 出版者 | BEILSTEIN-INSTITUT |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/72767]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yang, Guoqiang |
| 作者单位 | 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, CAS Key Lab Photochem, Beijing 100190, Peoples R China 2.Russian Acad Sci, Siberian Branch, AE Favorsky Irkutsk Inst Chem, Irkutsk 664033, Russia |
| 推荐引用方式 GB/T 7714 | Yang, Zhipei,Zhang, Kai,Gong, Fangbin,et al. A new fluorescent chemosensor for fluoride anion based on a pyrrole-isoxazole derivative[J]. BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY,2011,7:46-52. |
| APA | Yang, Zhipei.,Zhang, Kai.,Gong, Fangbin.,Li, Shayu.,Chen, Jun.,...&Trofimov, Boris A..(2011).A new fluorescent chemosensor for fluoride anion based on a pyrrole-isoxazole derivative.BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY,7,46-52. |
| MLA | Yang, Zhipei,et al."A new fluorescent chemosensor for fluoride anion based on a pyrrole-isoxazole derivative".BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY 7(2011):46-52. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。