Synthesis and Functionalization of Heteroatom-Bridged Bicyclocalixaromatics, Large Molecular Triangular Prisms with Electron-Rich and -Deficient Aromatic Interiors
文献类型：期刊论文
| 作者 | Naseer, Muhammad Moazzam1; Wang, De-Xian1; Zhao, Liang2; Huang, Zhi-Tang1; Wang, Mei-Xiang1,2 |
| 刊名 | JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | 2011-03-18 |
| 卷号 | 76期号:6页码:1804-1813 |
| ISSN号 | 0022-3263 |
| DOI | 10.1021/jo102483x |
| 英文摘要 | The synthesis and functionalization of oxygen and nitrogen atom bridged bicyclocalixaromatics of triangular prism structures are reported. By means of a fragment coupling approach, molecular triangular prisms of electron-rich and electron-deficient aromatic interiors were prepared using 1,3 5-tri(p-hydroxyphenyl)benzene and 2,4,6-tri(p-aminophenyl)triazine as base units and chlorotriazines as pillars. Aromatic nucleophilic substitution reaction of chlorotriazine moieties with functionalized amines led to triangular prisms with functionalizations on the peripheral edge positions, while functionalized triangular prisms on the vertex nitrogen positions were obtained using 2,4,6-tri[(p-allylamino)phenyl]triazine derivative as a starting material. Symmetrical and distorted molecular triangular prisms in the solid state were revealed by X-ray crystallography. As evidenced by NMR spectroscopic data, however, all cage molecules synthesized most probably adopted highly symmetric triangular prism structures in solution phase. The functionalized shape-persistent triangular prism structures might find applications in molecular recognition and in the construction of higher and more sophisticated molecular architectures in supramolecular chemistry. |
| 语种 | 英语 |
| WOS记录号 | WOS:000288142800033 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/72797]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Mei-Xiang |
| 作者单位 | 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Mol Recognit & Funct, Inst Chem, Beijing 100190, Peoples R China 2.Tsinghua Univ, Dept Chem, Key Lab Bioorgan Phosphorus Chem & Chem Biol, Minist Educ, Beijing 100084, Peoples R China |
| 推荐引用方式 GB/T 7714 | Naseer, Muhammad Moazzam,Wang, De-Xian,Zhao, Liang,et al. Synthesis and Functionalization of Heteroatom-Bridged Bicyclocalixaromatics, Large Molecular Triangular Prisms with Electron-Rich and -Deficient Aromatic Interiors[J]. JOURNAL OF ORGANIC CHEMISTRY,2011,76(6):1804-1813. |
| APA | Naseer, Muhammad Moazzam,Wang, De-Xian,Zhao, Liang,Huang, Zhi-Tang,&Wang, Mei-Xiang.(2011).Synthesis and Functionalization of Heteroatom-Bridged Bicyclocalixaromatics, Large Molecular Triangular Prisms with Electron-Rich and -Deficient Aromatic Interiors.JOURNAL OF ORGANIC CHEMISTRY,76(6),1804-1813. |
| MLA | Naseer, Muhammad Moazzam,et al."Synthesis and Functionalization of Heteroatom-Bridged Bicyclocalixaromatics, Large Molecular Triangular Prisms with Electron-Rich and -Deficient Aromatic Interiors".JOURNAL OF ORGANIC CHEMISTRY 76.6(2011):1804-1813. |
入库方式： OAI收割
来源：化学研究所
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