Two novel transition metal-organic frameworks based on 1,3,5-benzenetricarboxylate ligand: Syntheses, structures and thermal properties
文献类型：期刊论文
| 作者 | Fu, Ying1; Li, Guobao1; Liao, Fuhui1; Xiong, Ming2; Lin, Jianhua1 |
| 刊名 | JOURNAL OF MOLECULAR STRUCTURE
 |
| 出版日期 | 2011-10-12 |
| 卷号 | 1004期号:1-3页码:252-256 |
| 关键词 | Metal-organic Framework d(10) Transition Metal Hydrothermal Synthesis Structure Thermal Property 1 3 5-benzenetricarboxylic Acid |
| ISSN号 | 0022-2860 |
| DOI | 10.1016/j.molstruc.2011.08.013 |
| 英文摘要 | Two novel transition metal-organic frameworks, [Zn(6)(OH)(3)(BTC)(3)(H(2)O)(3)]center dot 7H(2)O (1) and [Cd(BTC)(H(2)O)]center dot[HIM] (2) (H(3)BTC = 1,3,5-benzenetricarboxylic acid), have been synthesized under hydrothermal conditions and characterized by single crystal and variable temperature powder X-ray diffraction (VTPXRD). IR spectroscopy, elemental analyses, ICP measurements, and coupled TG-MS analyses. Compound 1 crystallizes in the trigonal space group R3c, and could be described as a 3D porous network consisting of (Zn(2)O(8))(n) zigzag chains and bridging BTC ligands with 1D channels along c axis. Compound 2 crystallizes in the monoclinic space group P2(1)/c, and exhibits a 2D framework made up of CdO(6) octahedra and BTC ligands parallel the bc plane. TG-MS and VTPXRD studies reveal that 1 is stable up to 320 degrees C under air, and 2 stable up to 220 degrees C. (C) 2011 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000296927300033 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/72895]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Li, Guobao |
| 作者单位 | 1.Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing Natl Lab Mol Sci BNLMS, Beijing 100871, Peoples R China 2.China Univ Geosci, Xray Lab, Beijing 100083, Peoples R China |
| 推荐引用方式 GB/T 7714 | Fu, Ying,Li, Guobao,Liao, Fuhui,et al. Two novel transition metal-organic frameworks based on 1,3,5-benzenetricarboxylate ligand: Syntheses, structures and thermal properties[J]. JOURNAL OF MOLECULAR STRUCTURE,2011,1004(1-3):252-256. |
| APA | Fu, Ying,Li, Guobao,Liao, Fuhui,Xiong, Ming,&Lin, Jianhua.(2011).Two novel transition metal-organic frameworks based on 1,3,5-benzenetricarboxylate ligand: Syntheses, structures and thermal properties.JOURNAL OF MOLECULAR STRUCTURE,1004(1-3),252-256. |
| MLA | Fu, Ying,et al."Two novel transition metal-organic frameworks based on 1,3,5-benzenetricarboxylate ligand: Syntheses, structures and thermal properties".JOURNAL OF MOLECULAR STRUCTURE 1004.1-3(2011):252-256. |
入库方式： OAI收割
来源：化学研究所
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