Asymmetric Hydrogenation of 2-and 2,3-Substituted Quinoxalines with Chiral Cationic Ruthenium Diamine Catalysts
文献类型：期刊论文
| 作者 | Qin, Jie1,2; Chen, Fei1,2; Ding, Ziyuan1,2; He, Yan-Mei1,2; Xu, Lijin3; Fan, Qing-Hua1,2 |
| 刊名 | ORGANIC LETTERS
 |
| 出版日期 | 2011-12-16 |
| 卷号 | 13期号:24页码:6568-6571 |
| ISSN号 | 1523-7060 |
| DOI | 10.1021/ol2029096 |
| 英文摘要 | The enantioselective hydrogenation of 2-alkyl- and 2-aryl-subsituted quinoxalines and 2,3-disubstituted quinoxalines was developed by using the cationic Ru(eta(6)-cymene)(monosulfonylated diamine)(BArF) system in high yields with up to 99% ee. The counteranion was found to be critically important for the high enantioselectivity and/or diastereoselectivity. |
| 语种 | 英语 |
| WOS记录号 | WOS:000297717800061 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/72901]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Fan, Qing-Hua |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, CAS Key Lab Mol Recognit & Funct, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100190, Peoples R China 3.Renmin Univ China, Dept Chem, Beijing 100972, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qin, Jie,Chen, Fei,Ding, Ziyuan,et al. Asymmetric Hydrogenation of 2-and 2,3-Substituted Quinoxalines with Chiral Cationic Ruthenium Diamine Catalysts[J]. ORGANIC LETTERS,2011,13(24):6568-6571. |
| APA | Qin, Jie,Chen, Fei,Ding, Ziyuan,He, Yan-Mei,Xu, Lijin,&Fan, Qing-Hua.(2011).Asymmetric Hydrogenation of 2-and 2,3-Substituted Quinoxalines with Chiral Cationic Ruthenium Diamine Catalysts.ORGANIC LETTERS,13(24),6568-6571. |
| MLA | Qin, Jie,et al."Asymmetric Hydrogenation of 2-and 2,3-Substituted Quinoxalines with Chiral Cationic Ruthenium Diamine Catalysts".ORGANIC LETTERS 13.24(2011):6568-6571. |
入库方式： OAI收割
来源：化学研究所
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