Half-titanocenes for precise olefin polymerisation: effects of ligand substituents and some mechanistic aspects
文献类型：期刊论文
| 作者 | Nomura, Kotohiro1; Liu, Jingyu2 |
| 刊名 | DALTON TRANSACTIONS
 |
| 出版日期 | 2011-08-01 |
| 卷号 | 40期号:30页码:7666-7682 |
| ISSN号 | 1477-9226 |
| DOI | 10.1039/c1dt10086f |
| 英文摘要 | Selected examples concerning effects of both cyclopentadienyl fragment (Cp') and anionic donor ligand (Y) in nonbridged modified half-titanocenes of the type, Cp'TiX(2)(Y) (X = halogen, alkyl), as new type of olefin polymerisation catalysts have been reviewed. These complexes displayed unique characteristics not only for ethylene (co) polymerisation but also for syndiospecific styrene polymerisation, ethylene/styrene copolymerisation; precise fine tuning of the ligand substituents plays an important role for the successful (co) polymerisation; a different mechanistic consideration for the syndiospecific styrene polymerisation, which can explain the copolymerisation behaviour in this catalysis, has also been introduced. |
| 语种 | 英语 |
| WOS记录号 | WOS:000292972000002 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/72905]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Nomura, Kotohiro |
| 作者单位 | 1.Tokyo Metropolitan Univ, Dept Chem, Tokyo 1920397, Japan 2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Nomura, Kotohiro,Liu, Jingyu. Half-titanocenes for precise olefin polymerisation: effects of ligand substituents and some mechanistic aspects[J]. DALTON TRANSACTIONS,2011,40(30):7666-7682. |
| APA | Nomura, Kotohiro,&Liu, Jingyu.(2011).Half-titanocenes for precise olefin polymerisation: effects of ligand substituents and some mechanistic aspects.DALTON TRANSACTIONS,40(30),7666-7682. |
| MLA | Nomura, Kotohiro,et al."Half-titanocenes for precise olefin polymerisation: effects of ligand substituents and some mechanistic aspects".DALTON TRANSACTIONS 40.30(2011):7666-7682. |
入库方式： OAI收割
来源：化学研究所
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