中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Enrichment of metallic carbon nanotubes by electric field-assisted chemical vapor deposition

文献类型:期刊论文

作者Peng, Banghua1,2; Jiang, Shan1; Zhang, Yongyi1; Zhang, Jin1
刊名CARBON
出版日期2011-06-01
卷号49期号:7页码:2555-2560
ISSN号0008-6223
DOI10.1016/j.carbon.2011.02.045
英文摘要We report herein a rational approach to increase the proportion of metallic carbon nanotubes (CNTs) in horizontally aligned ultralong CNT arrays by electric field-assisted chemical vapor deposition. In a gas flow-directed growth mode, the buoyancy caused by temperature differences near the substrate can lift catalyst particles or CNTs from the substrate into the laminar flow so that ultralong CNT arrays with mixed metallic (m-) and semiconducting (s-) CNTs can be obtained. It was verified that the percentage of m-CNTs was about 47% for pristine CNTs. When an electric field was introduced during CNT growth, the grown CNTs were polarized and the generated electric field force assisted them into the laminar flow. The greater polarizability of m-CNTs compared to s-CNTs resulted in more m-CNTs lifted and an increased m- to s-CNT ratio in the array. Measurements of CNT electrical properties showed that the percentage of m-CNTs could reach 80% when the electric field intensity was set at 200 V/cm. (C) 2011 Elsevier Ltd. All rights reserved.
语种英语
WOS记录号WOS:000289663100044
出版者PERGAMON-ELSEVIER SCIENCE LTD
源URL[http://ir.iccas.ac.cn/handle/121111/72977]  
专题中国科学院化学研究所
通讯作者Zhang, Jin
作者单位1.Peking Univ, Coll Chem & Mol Engn, State Key Lab Struct Chem Unstable & Stable Speci, Ctr Nanochem,BNLMS,Key Lab Phys & Chem Nanodevice, Beijing 100871, Peoples R China
2.Shihezi Univ, Sch Chem & Chem Engn, Xinjiang 832000, Peoples R China
推荐引用方式
GB/T 7714
Peng, Banghua,Jiang, Shan,Zhang, Yongyi,et al. Enrichment of metallic carbon nanotubes by electric field-assisted chemical vapor deposition[J]. CARBON,2011,49(7):2555-2560.
APA Peng, Banghua,Jiang, Shan,Zhang, Yongyi,&Zhang, Jin.(2011).Enrichment of metallic carbon nanotubes by electric field-assisted chemical vapor deposition.CARBON,49(7),2555-2560.
MLA Peng, Banghua,et al."Enrichment of metallic carbon nanotubes by electric field-assisted chemical vapor deposition".CARBON 49.7(2011):2555-2560.

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来源:化学研究所

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