Synthesis, characteristics and photoluminescent properties of novel Ir-Eu heteronuclear complexes containing 2-carboxyl-pyrimidine as a bridging ligand
文献类型：期刊论文
| 作者 | Lian, Ping1,2; Wei, Huibo1; Zheng, Chen1; Nie, Yifan1; Bian, Jiang1; Bian, Zuqiang1; Huang, Chunhui1 |
| 刊名 | DALTON TRANSACTIONS
 |
| 出版日期 | 2011 |
| 卷号 | 40期号:20页码:5476-5482 |
| ISSN号 | 1477-9226 |
| DOI | 10.1039/c0dt01592j |
| 英文摘要 | Two novel iridium(III) complexes, [Ir(dfppy)(2)(pmc)] and [Ir(ppy)(2)(pmc)] (dfppy = 2-(4', 6'-difluoro-phenyl) pyridine, ppy = 1-phenyl-pyridine), were designed and synthesized using 2- carboxyl-pyrimidine (Hpmc) as an ancillary ligand. Single crystals were obtained and characterized by single crystal X-ray diffraction. The tetrametallic complexes {[((CN)-N-boolean AND)(2)Ir(mu-pmc)](3)EuCl3} ((CN)-N-boolean AND = dfppy, ppy) were synthesized using the iridium(III) complexes as "ligands". Photophysical and theoretical studies indicate that [Ir(dfppy) 2(pmc)] is more suitable for sensitizing the emission of Eu(III) ions than [Ir(ppy)(2)(pmc)]. |
| 语种 | 英语 |
| WOS记录号 | WOS:000290161900011 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/73087]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Bian, Zuqiang |
| 作者单位 | 1.Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China 2.Gannan Normal Univ, Coll Chem & Life Sci, Ganzhou 341000, Jiangxi, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lian, Ping,Wei, Huibo,Zheng, Chen,et al. Synthesis, characteristics and photoluminescent properties of novel Ir-Eu heteronuclear complexes containing 2-carboxyl-pyrimidine as a bridging ligand[J]. DALTON TRANSACTIONS,2011,40(20):5476-5482. |
| APA | Lian, Ping.,Wei, Huibo.,Zheng, Chen.,Nie, Yifan.,Bian, Jiang.,...&Huang, Chunhui.(2011).Synthesis, characteristics and photoluminescent properties of novel Ir-Eu heteronuclear complexes containing 2-carboxyl-pyrimidine as a bridging ligand.DALTON TRANSACTIONS,40(20),5476-5482. |
| MLA | Lian, Ping,et al."Synthesis, characteristics and photoluminescent properties of novel Ir-Eu heteronuclear complexes containing 2-carboxyl-pyrimidine as a bridging ligand".DALTON TRANSACTIONS 40.20(2011):5476-5482. |
入库方式： OAI收割
来源：化学研究所
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