Confined Growth of Poly(butylene succinate) in Its Miscible Blends with Poly(vinylidene fluoride): Morphology and Growth Kinetics
文献类型：期刊论文
| 作者 | Wang, Tianchang1; Li, Huihui2; Wang, Feng2; Yan, Shouke1,2; Schultz, Jerold M.3 |
| 刊名 | JOURNAL OF PHYSICAL CHEMISTRY B
 |
| 出版日期 | 2011-06-23 |
| 卷号 | 115期号:24页码:7814-7822 |
| ISSN号 | 1520-6106 |
| DOI | 10.1021/jp203680e |
| 英文摘要 | The morphology and confined crystallization behavior of poly(butylene succinate) (PBS) in miscible poly(vinylidene fluoride) (PVDF)/PBS blends has been studied using differential scanning calorimetry (DSC) and optical and atomic force microscopy (OM and AFM). It was found that PBS crystal lamellae nucleated and grew confined inside the matrix of PVDF spherulites. Crystallized PBS domains grow with an ellipsoidal outline within PVDF spherulites formed at a relatively high PVDF crystallization temperature (T(c,PVDF)), while circular domains, engulfing several PVDF spherulites, are seen when growing in the PVDF spherulites created at lower T(c,PVDF). The growth kinetics of PBS confined in the PVDF matrix was investigated under various conditions. The growth rate of PBS (G(PBS)) increases with decreasing crystallization temperature and increasing PBS content under a given PVDF crystallization temperature (T(c,VDF)). For T(c,PVDF) above 145 degrees C, G(PBS) decreases with T(c,PVDF) for both 50:50 and 30:70 PVDF/PBS blends. However, for T(c,PVDF) below 145 degrees C, 50:50 and 30:70 PVDF/PBS blends exhibit the opposite G(PBS) trend; that is, G(PBS) for the 50:50 blend decreases with decreasing T(c,PVDF), while for the 30:70 PVDF/PBS blend G(PBS) increases with decreasing T(c,PVDF). It is shown that this behavior cannot be associated with the effect of crossing the boundary of smaller PVDF spherulites formed at a lower temperature. Rather, the behavior appears to be related to the interleaving growth of PBS lamellae among PVDF lamellae or between bundles of PVDF lamellae (fibrils), as in situ AFM observation shows. It is found that the interconnectedness of the molten pockets within the PVDF spherulites, which depends on the PVDF crystallization temperature, is an important factor determining the growth kinetics of PBS confined within the PVDF scaffold. |
| 语种 | 英语 |
| WOS记录号 | WOS:000291709500012 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/73089]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yan, Shouke |
| 作者单位 | 1.Chinese Acad Sci, State Key Lab Polymer Phys & Chem, Inst Chem, Beijing 100190, Peoples R China 2.Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China 3.Univ Delaware, Dept Mat Sci & Engn, Newark, DE 19716 USA |
| 推荐引用方式 GB/T 7714 | Wang, Tianchang,Li, Huihui,Wang, Feng,et al. Confined Growth of Poly(butylene succinate) in Its Miscible Blends with Poly(vinylidene fluoride): Morphology and Growth Kinetics[J]. JOURNAL OF PHYSICAL CHEMISTRY B,2011,115(24):7814-7822. |
| APA | Wang, Tianchang,Li, Huihui,Wang, Feng,Yan, Shouke,&Schultz, Jerold M..(2011).Confined Growth of Poly(butylene succinate) in Its Miscible Blends with Poly(vinylidene fluoride): Morphology and Growth Kinetics.JOURNAL OF PHYSICAL CHEMISTRY B,115(24),7814-7822. |
| MLA | Wang, Tianchang,et al."Confined Growth of Poly(butylene succinate) in Its Miscible Blends with Poly(vinylidene fluoride): Morphology and Growth Kinetics".JOURNAL OF PHYSICAL CHEMISTRY B 115.24(2011):7814-7822. |
入库方式： OAI收割
来源：化学研究所
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