Solvent effect on the synthesis of MIL-96(Cr) and MIL-100(Cr)
文献类型：期刊论文
| 作者 | Long, Peipei1; Wu, Huawei1; Zhao, Qiang1; Wang, Yingxia2; Dong, Jinxiang1; Li, Jinping1 |
| 刊名 | MICROPOROUS AND MESOPOROUS MATERIALS
 |
| 出版日期 | 2011-07-01 |
| 卷号 | 142期号:2-3页码:489-493 |
| ISSN号 | 1387-1811 |
| 关键词 | Mil-96 Mil-100 Synthesis Hydrogen Storage Methane Storage |
| DOI | 10.1016/j.micromeso.2010.12.036 |
| 英文摘要 | In this study, the impact of different solvents on structure formation in the Cr/H(3)BTC system has been investigated. A new chromium trimesate, designated as MIL-96(Cr), has been synthesized under solvo-thermal conditions in the presence of 1,3,5-benzenetricarboxylic acid (trimesic acid or H(3)BTC) in a mixed solvent of H(2)O and CH(3)OH. This synthesis differs from the hydrothermal preparation of the other three analogues of the MIL-96 structural type (MIL-96(AI). MIL-96(Ga), and MIL-96(In)). MIL-96(Cr) represents another phase resulting from the coordination of Cr(3+) and H3BTC besides MIL-100(Cr). These two materials show similar thermal behavior. Gas desorption isotherms have shown that MIL-96(Cr) exhibits a hydrogen storage capacity of up to 8.55 mmol g(-1) at 77 K under 2 MPa and is able to absorb methane up to 3.84 mmol g(-1) at 273 K and 3.23 mmol g(-1) at 303 K under 2 MPa, while MIL-100(Cr) showed more promising results: 14 mmol g(-1) hydrogen at 77K and 1.8 MPa, 4.54 mmol g(-1) methane at 273 K and 2 MPa, and 3.49 mmol g(-1) methane at 303 K and 2 M Pa. (C) 2011 Elsevier Inc. All rights reserved. |
| 语种 | 英语 |
| 出版者 | ELSEVIER SCIENCE BV |
| WOS记录号 | WOS:000290198500009 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/73131]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Li, Jinping |
| 作者单位 | 1.Taiyuan Univ Technol, Res Inst Special Chem, Taiyuan 030024, Shanxi, Peoples R China 2.Peking Univ, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Coll Chem & Mol Engn, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Long, Peipei,Wu, Huawei,Zhao, Qiang,et al. Solvent effect on the synthesis of MIL-96(Cr) and MIL-100(Cr)[J]. MICROPOROUS AND MESOPOROUS MATERIALS,2011,142(2-3):489-493. |
| APA | Long, Peipei,Wu, Huawei,Zhao, Qiang,Wang, Yingxia,Dong, Jinxiang,&Li, Jinping.(2011).Solvent effect on the synthesis of MIL-96(Cr) and MIL-100(Cr).MICROPOROUS AND MESOPOROUS MATERIALS,142(2-3),489-493. |
| MLA | Long, Peipei,et al."Solvent effect on the synthesis of MIL-96(Cr) and MIL-100(Cr)".MICROPOROUS AND MESOPOROUS MATERIALS 142.2-3(2011):489-493. |
入库方式： OAI收割
来源：化学研究所
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