Physicochemical, self-assembly and field-effect transistor properties of anti- and syn- thienoacene isomers
文献类型：期刊论文
| 作者 | Li, Rongjin1,2; Dong, Huanli1; Zhan, Xiaowei1; Li, Hongxiang2; Wen, Shu-Hao3; Deng, Wei-Qiao3; Han, Ke-Li3; Hu, Wenping1 |
| 刊名 | JOURNAL OF MATERIALS CHEMISTRY
 |
| 出版日期 | 2011 |
| 卷号 | 21期号:30页码:11335-11339 |
| ISSN号 | 0959-9428 |
| DOI | 10.1039/c0jm04583g |
| 英文摘要 | The relationships between the molecular structure, self-assembly and charge transport properties of two fused-ring thienoacene isomers, a sickle-like syn isomer and a linear anti isomer, were studied from both an experimental and a theoretical perspective. Under the same self-assembly conditions, the syn isomer formed one-dimensional (1D) micro- and nanoribbons, while the anti isomer formed two-dimensional (2D) nanoplates (all were single crystals). The differences were assigned to the change in intermolecular interactions due to the tiny tuning of the molecular structures. The field-effect mobility in the single crystals of the syn isomer was about one-third as high as that of the anti isomer. The different transfer integrals of the isomers explained the observed different mobilities. This study opens a vivid window to examine the self-assembly and charge transport properties of organic semiconductors by using configurational isomers. |
| 语种 | 英语 |
| WOS记录号 | WOS:000292974400042 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/73173]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhan, Xiaowei |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Organ Solids, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Organ Chem, Shanghai 200032, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Rongjin,Dong, Huanli,Zhan, Xiaowei,et al. Physicochemical, self-assembly and field-effect transistor properties of anti- and syn- thienoacene isomers[J]. JOURNAL OF MATERIALS CHEMISTRY,2011,21(30):11335-11339. |
| APA | Li, Rongjin.,Dong, Huanli.,Zhan, Xiaowei.,Li, Hongxiang.,Wen, Shu-Hao.,...&Hu, Wenping.(2011).Physicochemical, self-assembly and field-effect transistor properties of anti- and syn- thienoacene isomers.JOURNAL OF MATERIALS CHEMISTRY,21(30),11335-11339. |
| MLA | Li, Rongjin,et al."Physicochemical, self-assembly and field-effect transistor properties of anti- and syn- thienoacene isomers".JOURNAL OF MATERIALS CHEMISTRY 21.30(2011):11335-11339. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。