Near-IR Electrochromism in Electropolymerized Films of a Biscyclometalated Ruthenium Complex Bridged by 1,2,4,5-Tetra(2-pyridyl)benzene
文献类型：期刊论文
| 作者 | Yao, Chang-Jiang1; Zhong, Yu-Wu1; Nie, Hai-Jing1; Abruna, Hector D.2; Yao, Jiannian1 |
| 刊名 | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
 |
| 出版日期 | 2011-12-28 |
| 卷号 | 133期号:51页码:20720-20723 |
| ISSN号 | 0002-7863 |
| DOI | 10.1021/ja209620p |
| 英文摘要 | Reductive electropolymerization of the biscyclometalated ruthenium complex [(vtpy)Ru(tpb)Ru-(vtpy)](2+) [vtpy = 4'-vinyl-2,2':6',2 ''-terpyridine; tpb = 1,2,4,5-tetra(2-pyridyl)benzene] proceeded smoothly on electrode surfaces. Thanks to the strong electron coupling between the ruthenium centers of the individual monomeric units and strong intervalence charge-transfer absorption in the mixed valence state, the produced adherent metallopolymeric films exhibited near-IR electrochromism with tricolor switching, good contrast ratio (40% at 1165 nm), short response time, low-switching voltage, and long memory time. |
| 语种 | 英语 |
| 出版者 | AMER CHEMICAL SOC |
| WOS记录号 | WOS:000298571600016 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/73241]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhong, Yu-Wu |
| 作者单位 | 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Photochem, Inst Chem, Beijing 100190, Peoples R China 2.Cornell Univ, Baker Lab, Dept Chem & Chem Biol, Ithaca, NY 14853 USA |
| 推荐引用方式 GB/T 7714 | Yao, Chang-Jiang,Zhong, Yu-Wu,Nie, Hai-Jing,et al. Near-IR Electrochromism in Electropolymerized Films of a Biscyclometalated Ruthenium Complex Bridged by 1,2,4,5-Tetra(2-pyridyl)benzene[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2011,133(51):20720-20723. |
| APA | Yao, Chang-Jiang,Zhong, Yu-Wu,Nie, Hai-Jing,Abruna, Hector D.,&Yao, Jiannian.(2011).Near-IR Electrochromism in Electropolymerized Films of a Biscyclometalated Ruthenium Complex Bridged by 1,2,4,5-Tetra(2-pyridyl)benzene.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,133(51),20720-20723. |
| MLA | Yao, Chang-Jiang,et al."Near-IR Electrochromism in Electropolymerized Films of a Biscyclometalated Ruthenium Complex Bridged by 1,2,4,5-Tetra(2-pyridyl)benzene".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 133.51(2011):20720-20723. |
入库方式： OAI收割
来源：化学研究所
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