Nanometer-Sized Reactor-A Porphyrin-Based Model System for Anion Species
文献类型：期刊论文
| 作者 | Li, Yong-jun1; Zhao, Ying-jie1; Flood, Amar H.2; Liu, Chao1; Liu, Hui-biao1; Li, Yu-liang1 |
| 刊名 | CHEMISTRY-A EUROPEAN JOURNAL
 |
| 出版日期 | 2011-06-01 |
| 卷号 | 17期号:27页码:7499-7505 |
| 关键词 | Anions Host-guest Systems Photosensitization Porphyrins Reactors |
| ISSN号 | 0947-6539 |
| DOI | 10.1002/chem.201100633 |
| 英文摘要 | Although many cagelike molecules can create a catalytic environment for promoting chemical reactions, the construction of receptors that can host anionic species and sensitize their reaction is novel. Here we report the photochemically induced dimerization of the anion radicals of TCNQ (7,7,8,8-tetracyano-para-quinodimethane) in organic solvent under aerobic conditions when they are encapsulated inside a cationic photoactive receptor. There is clear evidence for a rate increase of over two orders of magnitude, photosensitization of the host, and demonstrated turnover of the catalyst. |
| 语种 | 英语 |
| WOS记录号 | WOS:000292211300017 |
| 出版者 | WILEY-BLACKWELL |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/73325]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Li, Yong-jun |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Indiana Univ, Dept Chem, Bloomington, IN 47405 USA |
| 推荐引用方式 GB/T 7714 | Li, Yong-jun,Zhao, Ying-jie,Flood, Amar H.,et al. Nanometer-Sized Reactor-A Porphyrin-Based Model System for Anion Species[J]. CHEMISTRY-A EUROPEAN JOURNAL,2011,17(27):7499-7505. |
| APA | Li, Yong-jun,Zhao, Ying-jie,Flood, Amar H.,Liu, Chao,Liu, Hui-biao,&Li, Yu-liang.(2011).Nanometer-Sized Reactor-A Porphyrin-Based Model System for Anion Species.CHEMISTRY-A EUROPEAN JOURNAL,17(27),7499-7505. |
| MLA | Li, Yong-jun,et al."Nanometer-Sized Reactor-A Porphyrin-Based Model System for Anion Species".CHEMISTRY-A EUROPEAN JOURNAL 17.27(2011):7499-7505. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。