Synthesis and Photovoltaic Properties of Dithienyl Benzotriazole Based Poly(phenylene vinylene)s
文献类型:期刊论文
作者 | Zhang, Zhenhua1; Peng, Bo1; Ding, Ping1; Liu, Bo2; He, Yuehui2; Zhou, Kechao2; Li, Yongfang3; Pan, Chunyue1; Zou, Yingping1 |
刊名 | JOURNAL OF APPLIED POLYMER SCIENCE
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出版日期 | 2011-06-05 |
卷号 | 120期号:5页码:2534-2542 |
关键词 | Charge Transport Conducting Polymers Conjugated Polymers Uv-vis Spectroscopy |
ISSN号 | 0021-8995 |
DOI | 10.1002/app.33224 |
英文摘要 | Two new alternating copolymers based on dithienyl benzotriazole segment and phenylene vinyl unit were synthesized by Heck cross coupling method. The polymers exhibited broad absorption bands (from 300 nm to 752 nm for P1, and from 300 nm to 654 nm for P2) in the UV-visible region with optical bandgap ranging between 1.6 and 1.9 eV and proper electronic energy levels measured by cyclic voltammetry. The photovoltaic properties of the polymers as electron donors with 6.6-phenyl C61-butyric acid methyl ester as the electron acceptor in a bulk heterojunction structures were reported. Preliminary results showed moderate power conversion efficiency of 0.36% and 0.4%, respectively, under the illumination of AM 1.5, 100 mW/cm 2 with a device structure of ITO/PEDOT : PSS/polymer : PC(60)BM (1 : 3)/Ca/Al. Furthermore, the side chain effect on properties has also been investigated. (C) 2010 Wiley Periodicals, Inc. J Appl Polym Sci 120: 2534-2542, 2011 |
语种 | 英语 |
WOS记录号 | WOS:000288340100005 |
出版者 | WILEY-BLACKWELL |
源URL | [http://ir.iccas.ac.cn/handle/121111/73353] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Zou, Yingping |
作者单位 | 1.Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Peoples R China 2.Cent S Univ, State Key Lab Powder Met, Changsha 410083, Peoples R China 3.Chinese Acad Sci, Inst Chem, Key Lab Organ Solids, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, Zhenhua,Peng, Bo,Ding, Ping,et al. Synthesis and Photovoltaic Properties of Dithienyl Benzotriazole Based Poly(phenylene vinylene)s[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2011,120(5):2534-2542. |
APA | Zhang, Zhenhua.,Peng, Bo.,Ding, Ping.,Liu, Bo.,He, Yuehui.,...&Zou, Yingping.(2011).Synthesis and Photovoltaic Properties of Dithienyl Benzotriazole Based Poly(phenylene vinylene)s.JOURNAL OF APPLIED POLYMER SCIENCE,120(5),2534-2542. |
MLA | Zhang, Zhenhua,et al."Synthesis and Photovoltaic Properties of Dithienyl Benzotriazole Based Poly(phenylene vinylene)s".JOURNAL OF APPLIED POLYMER SCIENCE 120.5(2011):2534-2542. |
入库方式: OAI收割
来源:化学研究所
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