Synthesis and Characterization of Novel Semiconductors Based on Thieno[3,2-b][1]benzothiophene Cores and Their Applications in the Organic Thin-Film Transistors
文献类型:期刊论文
作者 | Chen, Huajie1,2; Cui, Qingyu1,3; Yu, Gui1; Guo, Yunlong1; Huang, Jianyao1,2; Zhu, Minliang1,2; Guo, Xiaojun3; Liu, Yunqi1 |
刊名 | JOURNAL OF PHYSICAL CHEMISTRY C
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出版日期 | 2011-12-08 |
卷号 | 115期号:48页码:23984-23991 |
ISSN号 | 1932-7447 |
DOI | 10.1021/jp2081484 |
英文摘要 | The synthesis and characterization of four new organic semiconductors with thieno[3,2-b][1]benzothiophene cores and different pi-bridge spacers are reported. Cyclic voltammetry measurement indicates that the materials have low energy levels of the highest occupied molecular orbitals and large band gaps. The single-crystal X-ray diffraction experiment reveals that 1,2-di(thieno [3,2-b][1]benzothiophenic-2-)ethylene (DTBTE) molecules have a nearly coplanar structure and crystallize into a herringbone arrangement with strongly intermolecular multiple S center dot center dot center dot S, S center dot center dot center dot C, and CH center dot center dot center dot pi interactions. These interactions facilitate charge carrier transport. The DTBTE-based organic thin-film transistors (OTFTs? on an octyltrichlorosilane-modified SiO(2)/Si substrate exhibit good field-effect performance with the highest mobility of 0.50 cm(2) V(-1) s(-1). Furthermore, the DTBTE-based OTFTs have been fabricated on a flexible polyethylene terephthalate substrate and showed a maximum mobility of up to 0.45 cm(2) V(-1) s(-1), indicating its potential application as an organic semiconductor in the flexible OTFTs. |
语种 | 英语 |
WOS记录号 | WOS:000297446300042 |
出版者 | AMER CHEMICAL SOC |
源URL | [http://ir.iccas.ac.cn/handle/121111/73403] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Yu, Gui |
作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China 3.Shanghai Jiao Tong Univ, Sch Elect Informat & Elect Engn, Ctr Optoelect Mat & Devices, Shanghai 200240, Peoples R China |
推荐引用方式 GB/T 7714 | Chen, Huajie,Cui, Qingyu,Yu, Gui,et al. Synthesis and Characterization of Novel Semiconductors Based on Thieno[3,2-b][1]benzothiophene Cores and Their Applications in the Organic Thin-Film Transistors[J]. JOURNAL OF PHYSICAL CHEMISTRY C,2011,115(48):23984-23991. |
APA | Chen, Huajie.,Cui, Qingyu.,Yu, Gui.,Guo, Yunlong.,Huang, Jianyao.,...&Liu, Yunqi.(2011).Synthesis and Characterization of Novel Semiconductors Based on Thieno[3,2-b][1]benzothiophene Cores and Their Applications in the Organic Thin-Film Transistors.JOURNAL OF PHYSICAL CHEMISTRY C,115(48),23984-23991. |
MLA | Chen, Huajie,et al."Synthesis and Characterization of Novel Semiconductors Based on Thieno[3,2-b][1]benzothiophene Cores and Their Applications in the Organic Thin-Film Transistors".JOURNAL OF PHYSICAL CHEMISTRY C 115.48(2011):23984-23991. |
入库方式: OAI收割
来源:化学研究所
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