Synthesis, characterization and ethylene (co-)polymerization behavior of half-titanocene 2-(1-(arylimino)ethyl)quinolin-8-olate chlorides
文献类型：期刊论文
| 作者 | Huang, Wei1,2; Li, Baixiang3; Wang, Youhong1,2; Zhang, Wenjuan1,2; Wang, Lin1,2; Li, Yuesheng3; Sun, Wen-Hua1,2 ; Redshaw, Carl4
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| 刊名 | CATALYSIS SCIENCE & TECHNOLOGY
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| 出版日期 | 2011 |
| 卷号 | 1期号:7页码:1208-1215 |
| ISSN号 | 2044-4753 |
| DOI | 10.1039/c1cy00193k |
| 英文摘要 | The series of half-titanocene 2-(1-(arylimino)ethyl)quinolin-8-olate dichlorides, Cp'TiCl(2)L (Cp' = eta(5)-C(5)H(5) or eta(5)-C(5)Me(5), L = 2-(1-(2,6-R(1)-4-R(2)-phenylimino)ethyl)quinolin-8-olate), was synthesized via the stoichiometric reaction of Cp'TiCl(3) with the corresponding potassium salt, viz. 2-(1-(2,6-R(1)-4-R(2)-phenylimino)ethyl)quinolin-8-olate. All compounds were characterized by elemental analysis, (1)H and (13)C NMR spectroscopy. The molecular structures of complexes C2 and C4 were determined by single-crystal X-ray diffraction. When activated with methylaluminoxane (MAO), all half-titanocene pre-catalysts exhibited high activities for ethylene polymerization and co-polymerization with alpha-olefins or norbornene. |
| 语种 | 英语 |
| WOS记录号 | WOS:000295000900018 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/73429]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Huang, Wei |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 4.Univ E Anglia, Sch Chem, Norwich NR4 7TJ, Norfolk, England |
| 推荐引用方式 GB/T 7714 | Huang, Wei,Li, Baixiang,Wang, Youhong,et al. Synthesis, characterization and ethylene (co-)polymerization behavior of half-titanocene 2-(1-(arylimino)ethyl)quinolin-8-olate chlorides[J]. CATALYSIS SCIENCE & TECHNOLOGY,2011,1(7):1208-1215. |
| APA | Huang, Wei.,Li, Baixiang.,Wang, Youhong.,Zhang, Wenjuan.,Wang, Lin.,...&Redshaw, Carl.(2011).Synthesis, characterization and ethylene (co-)polymerization behavior of half-titanocene 2-(1-(arylimino)ethyl)quinolin-8-olate chlorides.CATALYSIS SCIENCE & TECHNOLOGY,1(7),1208-1215. |
| MLA | Huang, Wei,et al."Synthesis, characterization and ethylene (co-)polymerization behavior of half-titanocene 2-(1-(arylimino)ethyl)quinolin-8-olate chlorides".CATALYSIS SCIENCE & TECHNOLOGY 1.7(2011):1208-1215. |
入库方式： OAI收割
来源：化学研究所
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