Synthesis of Thermo-Responsive Polymers With Both Tunable UCST and LCST
文献类型：期刊论文
| 作者 | Tian, Hai-Ying1; Yan, Jun-Jie1; Wang, Di1; Gu, Chen1; You, Ye-Zi1; Chen, Xue-Si2 |
| 刊名 | MACROMOLECULAR RAPID COMMUNICATIONS
 |
| 出版日期 | 2011-04-19 |
| 卷号 | 32期号:8页码:660-664 |
| 关键词 | Block Copolymers Lcst Raft Stimuli-responsive Polymers Ucst |
| ISSN号 | 1022-1336 |
| DOI | 10.1002/marc.201000713 |
| 英文摘要 | New water-soluble block copolymers of 2-(2-methoxyethoxy)ethyl methacrylate (MEO(2)MA), oligo(ethylene glycol) methacrylate (OEGMA), and N-(3-(dimethylamino) propyl) methacrylamide (DMAPMA) (poly(OEGMA-co-MEO(2)MA)-b-poly(DMAPMA)) were prepared via sequential reversible addition-fragmentation chain transfer (RAFT) polymerization. Selective quaternization of poly(DMAPMA) block gives poly(OEGMA-co-MEO2MA)-b-poly((3-[N-(3-methacrylamidopropyl)- N,N-dimethyl]ammoniopropane sulfonate)-co-N-(3-(dimethylamino) propyl) methacrylamide), such block copolymer exhibits double thermo-responsive behavior in water, poly(MEO(2)MA-co-OEGMA) block shows a lower critical solution temperature (LCST), and poly((3-[N-(3-methacrylamidopropyl)- N, N-dimethyl] ammoniopropane sulfonate)- co-N-(3-(dimethylamino) propyl) methacrylamide) block shows a upper critical solution temperature (UCST). Both of LCST and UCST can be controlled: LCST could be tuned by the fraction of OEGMA units in poly(OEGMA-co-MEO(2)MA), and UCST was found to be dependent on the degree of quaternization (DQ). |
| 语种 | 英语 |
| WOS记录号 | WOS:000289376200006 |
| 出版者 | WILEY-BLACKWELL |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/73455]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | You, Ye-Zi |
| 作者单位 | 1.Univ Sci & Technol China, CAS Key Lab Soft Matter Chem, Dept Polymer Sci & Engn, Hefei 230026, Peoples R China 2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tian, Hai-Ying,Yan, Jun-Jie,Wang, Di,et al. Synthesis of Thermo-Responsive Polymers With Both Tunable UCST and LCST[J]. MACROMOLECULAR RAPID COMMUNICATIONS,2011,32(8):660-664. |
| APA | Tian, Hai-Ying,Yan, Jun-Jie,Wang, Di,Gu, Chen,You, Ye-Zi,&Chen, Xue-Si.(2011).Synthesis of Thermo-Responsive Polymers With Both Tunable UCST and LCST.MACROMOLECULAR RAPID COMMUNICATIONS,32(8),660-664. |
| MLA | Tian, Hai-Ying,et al."Synthesis of Thermo-Responsive Polymers With Both Tunable UCST and LCST".MACROMOLECULAR RAPID COMMUNICATIONS 32.8(2011):660-664. |
入库方式： OAI收割
来源：化学研究所
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