Synthesis, Structures and Magnetism of Two New 3D Pillared-layer Cerium Mixed Carboxylate Porous Metal-organic Frameworks
文献类型：期刊论文
| 作者 | Zhu Wen-Hua1,2; Wang Zhe-Ming1; Gao Song1 |
| 刊名 | CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
 |
| 出版日期 | 2011-03-10 |
| 卷号 | 32期号:3页码:532-537 |
| 关键词 | Metal-organic Framework Cerium Complex Mixed Carboxylate Magnetism |
| ISSN号 | 0251-0790 |
| 英文摘要 | Two new cerium mixed carboxylate porous metal-organic frameworks, [Ce(2)(fum)(3)(H(2)O)(4)center dot(H(2)bdc)center dot(H(2)O)(2)](n) (1, H(2)fum = fumaric acid, H(2)bdc p-benzenedicarboxylic acid) and [Ce(2)(suc)(2)(ox) (H(2)O)(4)center dot(H(2)O)(4) (4) (2, H(2)suc = succinic acid, H(2)ox = oxalic acid) were synthesized by hydrothermal method with two kinds of carboxylic acid, respectively. They were characterized by elemental analysis, IR, TGA-DTA and single-crystal X-ray diffraction. Complexes 1 and 2 are both 3D porous metal-organic frameworks of pillared-layer type. Complex 1 possesses a 3D framework structure consisting of Ce-fumarate layers pillared by fumarate ligands with intersected channels in two directions between the layers occupied by uncoordinated neutral p-benzenedicarboxylic acid and lattice water molecules. Similar to complex 1, complex 2 is a 3D framework structure with Ce-succinate layers pillared by oxalate ligands, which shows intersected channels in three directions between the layers filled with lattice water molecules. |
| 语种 | 英语 |
| WOS记录号 | WOS:000289041600015 |
| 出版者 | HIGHER EDUCATION PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/73491]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang Zhe-Ming |
| 作者单位 | 1.Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China 2.Hubei Univ, Coll Chem & Chem Engn, Wuhan 430062, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhu Wen-Hua,Wang Zhe-Ming,Gao Song. Synthesis, Structures and Magnetism of Two New 3D Pillared-layer Cerium Mixed Carboxylate Porous Metal-organic Frameworks[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2011,32(3):532-537. |
| APA | Zhu Wen-Hua,Wang Zhe-Ming,&Gao Song.(2011).Synthesis, Structures and Magnetism of Two New 3D Pillared-layer Cerium Mixed Carboxylate Porous Metal-organic Frameworks.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,32(3),532-537. |
| MLA | Zhu Wen-Hua,et al."Synthesis, Structures and Magnetism of Two New 3D Pillared-layer Cerium Mixed Carboxylate Porous Metal-organic Frameworks".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 32.3(2011):532-537. |
入库方式： OAI收割
来源：化学研究所
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