Resonance-enhanced multiphoton ionization (REMPI) spectroscopy of the Cl-35 and Cl-37 isotopomers of p-chloroanisole
文献类型：期刊论文
| 作者 | Yu, Dan; Dong, Changwu; Cheng, Min; Hu, Lili; Du, Yikui; Zhu, Qihe; Zhang, Cunhao |
| 刊名 | JOURNAL OF MOLECULAR SPECTROSCOPY
 |
| 出版日期 | 2011-02-01 |
| 卷号 | 265期号:2页码:86-91 |
| 关键词 | R2pi P-chloroanisole Ab Initio Isotope Effect |
| ISSN号 | 0022-2852 |
| DOI | 10.1016/j.jms.2010.11.006 |
| 英文摘要 | The geometric structures and vibrations of p-chloroanisole isotopomers in the first electronically excited state were studied by mass-analyzed resonance-enhanced two-photon ionization spectroscopy and by theoretical calculations. The band origins of the S-1 <- S-0 electronic transitions of Cl-35 and Cl-37 isotopomers were found to be equivalent at 34 859 +/- 3 cm(-1). Assignments of the observed vibrational bands of the two isotopomers were made mainly based on the CIS/cc-PVDZ calculations and on conformity with the available data in the literature. Although the general spectral features of these two isotopomers are similar, the frequencies of some vibrational modes are different. This frequency shift partially depends on the degree of involvement of the chlorine atom in the molecular vibrations. (c) 2010 Elsevier Inc. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000288283000005 |
| 出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/73539]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Du, Yikui |
| 作者单位 | Chinese Acad Sci, Beijing Natl Lab Mol Sci, State Key Lab Mol React Dynam, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yu, Dan,Dong, Changwu,Cheng, Min,et al. Resonance-enhanced multiphoton ionization (REMPI) spectroscopy of the Cl-35 and Cl-37 isotopomers of p-chloroanisole[J]. JOURNAL OF MOLECULAR SPECTROSCOPY,2011,265(2):86-91. |
| APA | Yu, Dan.,Dong, Changwu.,Cheng, Min.,Hu, Lili.,Du, Yikui.,...&Zhang, Cunhao.(2011).Resonance-enhanced multiphoton ionization (REMPI) spectroscopy of the Cl-35 and Cl-37 isotopomers of p-chloroanisole.JOURNAL OF MOLECULAR SPECTROSCOPY,265(2),86-91. |
| MLA | Yu, Dan,et al."Resonance-enhanced multiphoton ionization (REMPI) spectroscopy of the Cl-35 and Cl-37 isotopomers of p-chloroanisole".JOURNAL OF MOLECULAR SPECTROSCOPY 265.2(2011):86-91. |
入库方式： OAI收割
来源：化学研究所
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