Organotin-oxomolybdate coordination polymer as catalyst for synthesis of unsymmetrical organic carbonates
文献类型：期刊论文
| 作者 | Song, Jinliang; Zhang, Binbin; Wu, Tainbin; Yang, Guanying; Han, Buxing |
| 刊名 | GREEN CHEMISTRY
 |
| 出版日期 | 2011 |
| 卷号 | 13期号:4页码:922-927 |
| ISSN号 | 1463-9262 |
| DOI | 10.1039/c0gc00765j |
| 英文摘要 | Efficient and greener synthesis of unsymmetrical organic carbonates is of great importance. In this work, two organotin-oxometalates, Bu(2)SnMoO(4) and (Bu(3)Sn)(2)MoO(4), were prepared and their catalytic performance for the transesterification of diethyl carbonate (DEC) with alcohols to synthesize unsymmetrical organic carbonates was studied. It was found that (Bu(3)Sn)(2)MoO(4) was very active and selective for the transesterification of DEC and various alcohols, including alkyl, cyclic, and aryl alcohols due to the synergetic effect between the groups of [MoO(4)](2) and [Bu(3)Sn](+) in the catalyst. The yields of the corresponding carbonates could reach 98% at the suitable conditions. The catalyst was reused five times and the activity and selectivity were not changed. We believe that the highly efficient, versatile, greener, inexpensive, selective and stable catalyst has great potential applications in the synthesis of various unsymmetrical organic carbonates from DEC and alcohols. |
| 语种 | 英语 |
| WOS记录号 | WOS:000289171900025 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/73665]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Song, Jinliang |
| 作者单位 | Chinese Acad Sci, Ctr Mol Sci, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Song, Jinliang,Zhang, Binbin,Wu, Tainbin,et al. Organotin-oxomolybdate coordination polymer as catalyst for synthesis of unsymmetrical organic carbonates[J]. GREEN CHEMISTRY,2011,13(4):922-927. |
| APA | Song, Jinliang,Zhang, Binbin,Wu, Tainbin,Yang, Guanying,&Han, Buxing.(2011).Organotin-oxomolybdate coordination polymer as catalyst for synthesis of unsymmetrical organic carbonates.GREEN CHEMISTRY,13(4),922-927. |
| MLA | Song, Jinliang,et al."Organotin-oxomolybdate coordination polymer as catalyst for synthesis of unsymmetrical organic carbonates".GREEN CHEMISTRY 13.4(2011):922-927. |
入库方式： OAI收割
来源：化学研究所
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