Linear and Cyclic Tetrathiafulvalene-Naphthalenediimide Donor-Acceptor Molecules: Metal Ions-Promoted Electron Transfer
文献类型:期刊论文
作者 | Tan, Luxi1,2; Zhang, Guanxin1; Zhang, Deqing1; Zhu, Daoben1 |
刊名 | JOURNAL OF ORGANIC CHEMISTRY |
出版日期 | 2011-11-04 |
卷号 | 76期号:21页码:9046-9052 |
ISSN号 | 0022-3263 |
DOI | 10.1021/jo201802p |
英文摘要 | Three linear and one cyclic tetrathiafulvalene-1,4,5,8-naphthalenediimide (TTF-NDI) compounds 1, 2, 3, and 4 were synthesized and studied in the presence of metal ions. Both absorption and electron spin resonance spectroscopic studies clearly indicate that electron transfer occurs from TTF to the NDI unit in the presence of metal ions (Pb2+ and Sc3+) for linear compounds 1 and 2. The mechanism based on the metal ion coordination is proposed for the electron transfer within 1 and 2 after the addition of metal ions. Compound 3 exhibits intramolecular charge-transfer absorption because of the cydophane framework. Interestingly, intramolecular electron transfer also takes place for 3 after the addition of either Sc3+ or Pb2+. |
语种 | 英语 |
出版者 | AMER CHEMICAL SOC |
WOS记录号 | WOS:000296206400045 |
源URL | [http://ir.iccas.ac.cn/handle/121111/73711] |
专题 | 中国科学院化学研究所 |
通讯作者 | Zhang, Deqing |
作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Organ Solids Lab, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Tan, Luxi,Zhang, Guanxin,Zhang, Deqing,et al. Linear and Cyclic Tetrathiafulvalene-Naphthalenediimide Donor-Acceptor Molecules: Metal Ions-Promoted Electron Transfer[J]. JOURNAL OF ORGANIC CHEMISTRY,2011,76(21):9046-9052. |
APA | Tan, Luxi,Zhang, Guanxin,Zhang, Deqing,&Zhu, Daoben.(2011).Linear and Cyclic Tetrathiafulvalene-Naphthalenediimide Donor-Acceptor Molecules: Metal Ions-Promoted Electron Transfer.JOURNAL OF ORGANIC CHEMISTRY,76(21),9046-9052. |
MLA | Tan, Luxi,et al."Linear and Cyclic Tetrathiafulvalene-Naphthalenediimide Donor-Acceptor Molecules: Metal Ions-Promoted Electron Transfer".JOURNAL OF ORGANIC CHEMISTRY 76.21(2011):9046-9052. |
入库方式: OAI收割
来源:化学研究所
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