Polymorphism of Amino Acid-Based Dendrons: From Organogels to Microcrystals
文献类型:期刊论文
作者 | Kuang, Gui-Chao1,2; Teng, Ming-Jun1,2; Jia, Xin-Ru1,2; Chen, Er-Qiang1,2; Wei, Yen3 |
刊名 | CHEMISTRY-AN ASIAN JOURNAL
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出版日期 | 2011-05-02 |
卷号 | 6期号:5页码:1163-1170 |
关键词 | Amino Acids Beta Sheets Dendrons Polymorphism Self-assembly |
ISSN号 | 1861-4728 |
DOI | 10.1002/asia.201000529 |
英文摘要 | There is a delicate balance for a low-weight molecule to behave as a gelator or crystal. The synthesis of two novel amino acid-based naphthalene-dendrons, Nap-G1 and Nap-G2 is described. Both dendrons display polymorphic properties in organic solvents. Nap-G1 developed a fibrous network with beta-sheet architecture in cyclohexane but exhibited a spherulitic network in mixed solvents (chloroform/petroleum ether 1: 5, v/v). On the other hand, Nap-G2 acted as an efficient organogelator in chloroform but formed crystalline fibers in relatively high polarity solvents (such as acetone and methanol). Combinations of characterizations have been employed to study the polymorphism. |
语种 | 英语 |
WOS记录号 | WOS:000290470600007 |
出版者 | WILEY-BLACKWELL |
源URL | [http://ir.iccas.ac.cn/handle/121111/73809] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Jia, Xin-Ru |
作者单位 | 1.Peking Univ, Coll Chem & Mol Engn, Minist Educ, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China 2.Peking Univ, Coll Chem & Mol Engn, Minist Educ, Key Lab Polymer Chem & Phys, Beijing 100871, Peoples R China 3.Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China |
推荐引用方式 GB/T 7714 | Kuang, Gui-Chao,Teng, Ming-Jun,Jia, Xin-Ru,et al. Polymorphism of Amino Acid-Based Dendrons: From Organogels to Microcrystals[J]. CHEMISTRY-AN ASIAN JOURNAL,2011,6(5):1163-1170. |
APA | Kuang, Gui-Chao,Teng, Ming-Jun,Jia, Xin-Ru,Chen, Er-Qiang,&Wei, Yen.(2011).Polymorphism of Amino Acid-Based Dendrons: From Organogels to Microcrystals.CHEMISTRY-AN ASIAN JOURNAL,6(5),1163-1170. |
MLA | Kuang, Gui-Chao,et al."Polymorphism of Amino Acid-Based Dendrons: From Organogels to Microcrystals".CHEMISTRY-AN ASIAN JOURNAL 6.5(2011):1163-1170. |
入库方式: OAI收割
来源:化学研究所
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