Monosubstituted arylimido hexamolybdates containing pendant amino groups: synthesis and structural characterization
文献类型：期刊论文
| 作者 | Zhu, Yi1; Xiao, Zicheng1,2; Wang, Longsheng2; Yin, Panchao2; Hao, Jian2; Wei, Yongge1,2,3; Wang, Yuan1 |
| 刊名 | DALTON TRANSACTIONS
 |
| 出版日期 | 2011-07-28 |
| 卷号 | 40期号:28页码:7304-7309 |
| ISSN号 | 1477-9226 |
| DOI | 10.1039/c1dt10168d |
| 英文摘要 | Three novel rigid-rod conjugated organic-POM hybrids (1, 2 and 3) containing pendant amino terminus, with different rod lengths and different substituents on the rod, have been respectively synthesized via one-pot reaction of hexamolybdate and the corresponding aromatic diamine (for 1 and 2) and reaction of octamolybdate and the corresponding aromatic diamine dihydrochloride (for 3) with N,N'-dicyclohexylcarbodiimide (DCC) as a dehydrating agent. These complexes have been characterized by UV/Vis, IR, (1)H NMR, ESI and single-crystal X-ray diffraction techniques. The influences of the rod length and substituents on the properties of these compounds have been systematically investigated, which provide necessary information for further preparations of complicated hybrid materials via reactions with pendant amino groups. |
| 语种 | 英语 |
| WOS记录号 | WOS:000292987200005 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/73907]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wei, Yongge |
| 作者单位 | 1.Peking Univ, Dept Chem, State Key Lab Struct Chem Unstable & Stable Speci, Coll Chem & Mol Engn, Beijing 100871, Peoples R China 2.Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China 3.Beijing Inst Technol, Key Lab Cluster Sci, Minist Educ China, Beijing 100081, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhu, Yi,Xiao, Zicheng,Wang, Longsheng,et al. Monosubstituted arylimido hexamolybdates containing pendant amino groups: synthesis and structural characterization[J]. DALTON TRANSACTIONS,2011,40(28):7304-7309. |
| APA | Zhu, Yi.,Xiao, Zicheng.,Wang, Longsheng.,Yin, Panchao.,Hao, Jian.,...&Wang, Yuan.(2011).Monosubstituted arylimido hexamolybdates containing pendant amino groups: synthesis and structural characterization.DALTON TRANSACTIONS,40(28),7304-7309. |
| MLA | Zhu, Yi,et al."Monosubstituted arylimido hexamolybdates containing pendant amino groups: synthesis and structural characterization".DALTON TRANSACTIONS 40.28(2011):7304-7309. |
入库方式： OAI收割
来源：化学研究所
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