The crystallization behavior of poly(ethylene glycol)-poly(epsilon-caprolactone) diblock copolymers with asymmetric block compositions
文献类型：期刊论文
| 作者 | Sun, Jingru1; He, Chaoliang1; Zhuang, Xiuli1; Jing, Xiabin2; Chen, Xuesi1 |
| 刊名 | JOURNAL OF POLYMER RESEARCH
 |
| 出版日期 | 2011-11-01 |
| 卷号 | 18期号:6页码:2161-2168 |
| 关键词 | Poly(Ethylene Glycol) Poly(Epsilon-caprolactone) Block Copolymer Crystallization Single Crystal |
| ISSN号 | 1022-9760 |
| DOI | 10.1007/s10965-011-9626-2 |
| 英文摘要 | Crystallization behavior, structural development and morphology evolution of a series of poly (ethylene glycol)-poly(epsilon-caprolactone) diblock copolymers (PEG-b-PCL) were investigated via differential scanning calorimetry (DSC), X-ray diffraction (XRD) and atomic force microscopy (AFM). In these copolymers, both blocks were crystallizable and biocompatible. The mutual effects between the PEG and PCL blocks were significant, leading to the obvious block composition dependence of the crystallization behavior and morphology of the PEG-b-PCL copolymers. The relative block length determined which block crystallized first. The temperature-dependent XRD measurements confirmed which block crystallized first from the copolymer during the cooling procedure. Single crystals of the PCL and PEG homopolymers and the PEG-b-PCL copolymers were obtained and observed by AFM. The block (PCL or PEG) crystallized first would determine the crystal morphology. The block crystallized later acted as a solvent, which was advantageous to forming perfect single crystals of the whole block copolymers. |
| 语种 | 英语 |
| WOS记录号 | WOS:000297352000098 |
| 出版者 | SPRINGER |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/73969]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Chen, Xuesi |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, Key Lab Polymer Ecomat, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sun, Jingru,He, Chaoliang,Zhuang, Xiuli,et al. The crystallization behavior of poly(ethylene glycol)-poly(epsilon-caprolactone) diblock copolymers with asymmetric block compositions[J]. JOURNAL OF POLYMER RESEARCH,2011,18(6):2161-2168. |
| APA | Sun, Jingru,He, Chaoliang,Zhuang, Xiuli,Jing, Xiabin,&Chen, Xuesi.(2011).The crystallization behavior of poly(ethylene glycol)-poly(epsilon-caprolactone) diblock copolymers with asymmetric block compositions.JOURNAL OF POLYMER RESEARCH,18(6),2161-2168. |
| MLA | Sun, Jingru,et al."The crystallization behavior of poly(ethylene glycol)-poly(epsilon-caprolactone) diblock copolymers with asymmetric block compositions".JOURNAL OF POLYMER RESEARCH 18.6(2011):2161-2168. |
入库方式： OAI收割
来源：化学研究所
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