THE APPLICATION OF STRUCTURAL DATA TO THE RESEARCH ON CHEMICAL REACTION PATHWAYS, I. DYNAMIC STEREOCHEMISTRY OF FIVE-COORDINATE MOLYBDENUM COMPOUNDS Mo(L)(5)
文献类型：期刊论文
| 作者 | Liao Daiqing; Fu Heng; Tang Yougi |
| 刊名 | ACTA PHYSICO-CHIMICA SINICA
 |
| 出版日期 | 1987 |
| 卷号 | 3期号:5页码:449-452 |
| ISSN号 | 1000-6818 |
| DOI | 10.3866/PKU.WHXB19870501 |
| 英文摘要 | The principle of structure correlation is applied to 28 crystal structures which contain 44 different five coordinate molybdenum fragments. The tints derived map the reaction pathway for a bimolecular ligand substitution reaction at tetrahedral molybdenum centers. The dihedral angle method from Muetteries and Guggenberger is employed in order to describe the interconversion between the trigonal bipyramidal (TBP) and tit square pramidal (SQP) conformations via the Berry pseudorotation mechanism in the system of Mo (L)(5) complexes. The structure correlation method provides a convincing mapping of the Berry pathway in this paper. |
| 语种 | 英语 |
| WOS记录号 | WOS:000207569500001 |
| 出版者 | PEKING UNIV PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/73989]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liao Daiqing |
| 作者单位 | Acad Sinica, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liao Daiqing,Fu Heng,Tang Yougi. THE APPLICATION OF STRUCTURAL DATA TO THE RESEARCH ON CHEMICAL REACTION PATHWAYS, I. DYNAMIC STEREOCHEMISTRY OF FIVE-COORDINATE MOLYBDENUM COMPOUNDS Mo(L)(5)[J]. ACTA PHYSICO-CHIMICA SINICA,1987,3(5):449-452. |
| APA | Liao Daiqing,Fu Heng,&Tang Yougi.(1987).THE APPLICATION OF STRUCTURAL DATA TO THE RESEARCH ON CHEMICAL REACTION PATHWAYS, I. DYNAMIC STEREOCHEMISTRY OF FIVE-COORDINATE MOLYBDENUM COMPOUNDS Mo(L)(5).ACTA PHYSICO-CHIMICA SINICA,3(5),449-452. |
| MLA | Liao Daiqing,et al."THE APPLICATION OF STRUCTURAL DATA TO THE RESEARCH ON CHEMICAL REACTION PATHWAYS, I. DYNAMIC STEREOCHEMISTRY OF FIVE-COORDINATE MOLYBDENUM COMPOUNDS Mo(L)(5)".ACTA PHYSICO-CHIMICA SINICA 3.5(1987):449-452. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。