A Primary Study of the Formation and Photolysis of Tantalum Sulfide Cluster Ions
文献类型:期刊论文
作者 | Zhang Nan; Yu Zhongde; Wu Xiaojun; Gao Zhen; Zhu Qihe; Kong Fan'ao |
刊名 | ACTA PHYSICO-CHIMICA SINICA
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出版日期 | 1994 |
卷号 | 10期号:1页码:44-49 |
关键词 | Tantalum Sulfide Cluster Ions Uv-photolysis Tandem Time-of-flight Mass Spectrometer |
ISSN号 | 1000-6818 |
DOI | 10.3866/PKU.WHXB19940111 |
英文摘要 | Tantalum sulfide cluster ions (TanSm+, n <= 9, m <= 30) were produced by direct ablation of a mixture of tantalum and sulfur powders and studied by a tandem timemass spectrometer. It was found that the most stable tantalum sulfide cluster ions TanS2n+7+, (n = 1-9). The main dissociation channel of the UV-photolysis (248nm.) sulfide cluster ions is sequent S-2 loss. For cluster ions with n >= 3, besides the channel, the photolysis yields Ta3S4+, or Ta4S6+, as the major product. A structure Ta3S4, or Ta4S6, as nucleus was suggested for large tantalum sulfide cluster ions. |
语种 | 英语 |
WOS记录号 | WOS:000207588800011 |
出版者 | PEKING UNIV PRESS |
源URL | [http://ir.iccas.ac.cn/handle/121111/73991] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Zhang Nan |
作者单位 | Chinese Acad Sci, Inst Chem, Lab Mol React Dynam, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang Nan,Yu Zhongde,Wu Xiaojun,et al. A Primary Study of the Formation and Photolysis of Tantalum Sulfide Cluster Ions[J]. ACTA PHYSICO-CHIMICA SINICA,1994,10(1):44-49. |
APA | Zhang Nan,Yu Zhongde,Wu Xiaojun,Gao Zhen,Zhu Qihe,&Kong Fan'ao.(1994).A Primary Study of the Formation and Photolysis of Tantalum Sulfide Cluster Ions.ACTA PHYSICO-CHIMICA SINICA,10(1),44-49. |
MLA | Zhang Nan,et al."A Primary Study of the Formation and Photolysis of Tantalum Sulfide Cluster Ions".ACTA PHYSICO-CHIMICA SINICA 10.1(1994):44-49. |
入库方式: OAI收割
来源:化学研究所
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