Study on the Intramolecular Electron Transfer of TTP-(CH2)(4)-Pc
文献类型：期刊论文
| 作者 | Chen Jianxin1; Tian Hongjian2; Zhang Honghao1; Zhou Qiangfu2; Hu Huijun2; Xu Guangzhi1 |
| 刊名 | ACTA PHYSICO-CHIMICA SINICA
 |
| 出版日期 | 1996 |
| 卷号 | 12期号:1页码:12-17 |
| 关键词 | Porphyrin-phthalocyanine Electron Transfer Time Correlated Single Photon Couting Fluorescence |
| ISSN号 | 1000-6818 |
| DOI | 10.3866/PKU.WHXB19960104 |
| 英文摘要 | The intramolecular electron transfer of TTP-(CH2)(n)-Pc ws studied by means of time correlated single photon counting method. When the Pc subunit of the compound is excited, the fluorescence of the compound is quenched by intramolecular electron transfer and the electron transfer is most favorable in the compound with n-4. When the TTP subunit of the compound is excited, the flourescence decay of the compound will be biexponential, which shows the existence of an electron transfer process. Some kinetic parameters were derived from the experimental data. With n increasing, the activation energy and the reorganization energy increase whereas the electron transfer rate decreases. Moreover, the free enthalpy change of electron transfer reaction Delta G(es) and the charge-separated rate k(CS) are in the order of: |
| 语种 | 英语 |
| WOS记录号 | WOS:000207591300004 |
| 出版者 | PEKING UNIV PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/74047]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Chen Jianxin |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Inst Photog Chem, Beijing 100101, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen Jianxin,Tian Hongjian,Zhang Honghao,et al. Study on the Intramolecular Electron Transfer of TTP-(CH2)(4)-Pc[J]. ACTA PHYSICO-CHIMICA SINICA,1996,12(1):12-17. |
| APA | Chen Jianxin,Tian Hongjian,Zhang Honghao,Zhou Qiangfu,Hu Huijun,&Xu Guangzhi.(1996).Study on the Intramolecular Electron Transfer of TTP-(CH2)(4)-Pc.ACTA PHYSICO-CHIMICA SINICA,12(1),12-17. |
| MLA | Chen Jianxin,et al."Study on the Intramolecular Electron Transfer of TTP-(CH2)(4)-Pc".ACTA PHYSICO-CHIMICA SINICA 12.1(1996):12-17. |
入库方式： OAI收割
来源：化学研究所
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