Het Photoelectron Spectroscopic Study of the Electronic Structure on B(OCH3)(3)
文献类型：期刊论文
| 作者 | Li Sheng1; Li Ying1; Wang Xiaohui1; Ding Chuanfan2; Chen Wenwu2; Gao Yiqin2; Wang Dianxun1 |
| 刊名 | ACTA PHYSICO-CHIMICA SINICA
 |
| 出版日期 | 1996 |
| 卷号 | 12期号:7页码:641-643 |
| 关键词 | Hel Photoelectron Spectroscopy (Pes) Trimethyl Borate Mndo Calculation |
| ISSN号 | 1000-6818 |
| DOI | 10.3866/PKU.WHXB19960712 |
| 英文摘要 | Hel photoelectron sportrum of B(OCH3)(3) is presented in this rumen The assignment of the spectrum has been also done by an analysis of the intensity of the spectrum bands and the optimized MNDO molecular orbital calculation on B(OCH3)(3) molecule. The split showing a 1.08eV of the bands at the lowest two ionization potentials (IPs) was assigned to the Jahn-Teller split or the doubly degenerate oxygen lone-pair orbitals, And the splits showing 0.42eV and 0.380eV on the above-mentioned bands were considered as the result of spin-orbital interaction Therefore the tins PES study provides an exceedingly experimental example to testify the Jahn-Teller effect and the spin-orbital interaction splitting. |
| 语种 | 英语 |
| WOS记录号 | WOS:000207600000012 |
| 出版者 | PEKING UNIV PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/74057]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Li Sheng |
| 作者单位 | 1.Acad Sinica, Inst Chem, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100080, Peoples R China 2.Acad Sinica, Inst Chem, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li Sheng,Li Ying,Wang Xiaohui,et al. Het Photoelectron Spectroscopic Study of the Electronic Structure on B(OCH3)(3)[J]. ACTA PHYSICO-CHIMICA SINICA,1996,12(7):641-643. |
| APA | Li Sheng.,Li Ying.,Wang Xiaohui.,Ding Chuanfan.,Chen Wenwu.,...&Wang Dianxun.(1996).Het Photoelectron Spectroscopic Study of the Electronic Structure on B(OCH3)(3).ACTA PHYSICO-CHIMICA SINICA,12(7),641-643. |
| MLA | Li Sheng,et al."Het Photoelectron Spectroscopic Study of the Electronic Structure on B(OCH3)(3)".ACTA PHYSICO-CHIMICA SINICA 12.7(1996):641-643. |
入库方式： OAI收割
来源：化学研究所
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