A study of Excited States of Acetyl Radical
文献类型：期刊论文
| 作者 | Li Qiang1; Mao Wentao1; Li Hongzhi1; Zhu Qihe1; Kong Fanao1; Huang Mingbao2 |
| 刊名 | ACTA PHYSICO-CHIMICA SINICA
 |
| 出版日期 | 1997 |
| 卷号 | 13期号:10页码:879-884 |
| 关键词 | Acetyl Radical(Ch3co) Electronically Excited State Photolysis Ir Emission Spectrum |
| ISSN号 | 1000-6818 |
| DOI | 10.3866/PKU.WHXB19971004 |
| 英文摘要 | Excited states of the acetyl radical (CH3CO) have been studied by means of theoretical and experimental methods. The four low-lying excited states (A 1(2) A", B 2(2) A', C 3(2) A', and D 2(2) A") and their vertical excitation energies have been calculated at the MP2 and MRSDCI levels. Thermal decomposition of the ground state of CH3CO and photodissociation of the first and second states (A 1(2) A" and B 2(2) A') have been investigated by Time-Resolved Fourier Transform Infrared Emission Spectroscopy. Vibrational products CO( ) have been observed. The first electronically excited state (A 1(2) A") of CH3CO is a bound state, and the second electronically excited state (B 2(2) A') of CH3CO is a predissociation state. |
| 语种 | 英语 |
| WOS记录号 | WOS:000207602000004 |
| 出版者 | PEKING UNIV PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/74091]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Li Qiang |
| 作者单位 | 1.Acad Sinica, Inst Chem, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China 2.Acad Sinica, USTC, Grad Sch Beijing, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li Qiang,Mao Wentao,Li Hongzhi,et al. A study of Excited States of Acetyl Radical[J]. ACTA PHYSICO-CHIMICA SINICA,1997,13(10):879-884. |
| APA | Li Qiang,Mao Wentao,Li Hongzhi,Zhu Qihe,Kong Fanao,&Huang Mingbao.(1997).A study of Excited States of Acetyl Radical.ACTA PHYSICO-CHIMICA SINICA,13(10),879-884. |
| MLA | Li Qiang,et al."A study of Excited States of Acetyl Radical".ACTA PHYSICO-CHIMICA SINICA 13.10(1997):879-884. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。