Combustion Enthalpies of C-60 and C-70 by Micro-oxygen-bomb Calorimetry
文献类型：期刊论文
| 作者 | An Xuwu; Chen Bin; He Jun |
| 刊名 | ACTA PHYSICO-CHIMICA SINICA
 |
| 出版日期 | 1997 |
| 卷号 | 13期号:11页码:961-964 |
| 关键词 | C-60 C-70 Micro-oxygeng-bomb Calorimeter Combustion Enthalpy Strain Energy |
| ISSN号 | 1000-6818 |
| DOI | 10.3866/PKU.WHXB19971101 |
| 英文摘要 | A micro-oxygen-bomb calorimeter with a bomb of 4.8 cm(3) internal volume was constructed in in laboratory. About 10 mg of sample was needed for each combustion experiment. Tint energy equivalent to calorimeter was determined with electric energy. TIE, standard diviation of mean from 5 measurements was 0.02 %. The enthalpies of combustion of pine C-60 mid C-70 were determined, Delta U-c(m)0(C-60, cr) = -(25947.1+/-8.5) kJ.mol(-1), Delta U-c(m)0(C-70, cr)=-(29950.1+/-8.9) kJ.mol(-1). The enthalpies of formation of the two compounds were derived. Using the Laidler-type bond parameters for aromatic hydrocarbons, the estimated strain energies in C-60 and C-70 molecules were close each other and close to the estimated value from the model compound. caranuclene. |
| 语种 | 英语 |
| WOS记录号 | WOS:000207602100001 |
| 出版者 | PEKING UNIV PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/74125]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | An Xuwu |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | An Xuwu,Chen Bin,He Jun. Combustion Enthalpies of C-60 and C-70 by Micro-oxygen-bomb Calorimetry[J]. ACTA PHYSICO-CHIMICA SINICA,1997,13(11):961-964. |
| APA | An Xuwu,Chen Bin,&He Jun.(1997).Combustion Enthalpies of C-60 and C-70 by Micro-oxygen-bomb Calorimetry.ACTA PHYSICO-CHIMICA SINICA,13(11),961-964. |
| MLA | An Xuwu,et al."Combustion Enthalpies of C-60 and C-70 by Micro-oxygen-bomb Calorimetry".ACTA PHYSICO-CHIMICA SINICA 13.11(1997):961-964. |
入库方式： OAI收割
来源：化学研究所
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