An ESR Study of Radical Intermediates in Electroreduction of Propargyl Alcohol
文献类型：期刊论文
| 作者 | Kuang Yafei1; Li Guoxi1; Huang Shukun1; Lu Daohui2; Chen Dewen2 |
| 刊名 | ACTA PHYSICO-CHIMICA SINICA
 |
| 出版日期 | 1997 |
| 卷号 | 13期号:10页码:954-956 |
| 关键词 | Propargyl Alcohol Electroreduction Electrochemical-esr Spin Trapping |
| ISSN号 | 1000-6818 |
| DOI | 10.3866/PKU.WHXB19971019 |
| 英文摘要 | Electrochemical-ESR technique (ex situ method) with spin traps phenyl text-butyl-nitrone (PBN) and 5,5-dimethyl-1-pyrroline-1-oxide (DMPO) has been applied to the detection of radical intermediates produced during electroreduction of propargyl alcohol (PA) at platinized platinum electrode in an acidified alcohol-aqua solution. Propargyl radical and H have been detected by PBN and DMPO, respectively. As a result of the discovery of these radicals, an evidence for a radical mechanism of the electroreduction of PA put forward by some authors might to obtained beyond all doubt. |
| 语种 | 英语 |
| WOS记录号 | WOS:000207602000019 |
| 出版者 | PEKING UNIV PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/74135]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Kuang Yafei |
| 作者单位 | 1.Hunan Univ, Coll Chem & Chem Engn, Changsha 410082, Hunan, Peoples R China 2.Acad Sinica, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Kuang Yafei,Li Guoxi,Huang Shukun,et al. An ESR Study of Radical Intermediates in Electroreduction of Propargyl Alcohol[J]. ACTA PHYSICO-CHIMICA SINICA,1997,13(10):954-956. |
| APA | Kuang Yafei,Li Guoxi,Huang Shukun,Lu Daohui,&Chen Dewen.(1997).An ESR Study of Radical Intermediates in Electroreduction of Propargyl Alcohol.ACTA PHYSICO-CHIMICA SINICA,13(10),954-956. |
| MLA | Kuang Yafei,et al."An ESR Study of Radical Intermediates in Electroreduction of Propargyl Alcohol".ACTA PHYSICO-CHIMICA SINICA 13.10(1997):954-956. |
入库方式： OAI收割
来源：化学研究所
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