Influence of metal ions on hydrogenation of o-chloronitrobenzene over platinum colloidal clusters
文献类型：期刊论文
| 作者 | Yang, XL; Liu, HF |
| 刊名 | APPLIED CATALYSIS A-GENERAL
 |
| 出版日期 | 1997-12-23 |
| 卷号 | 164期号:1-2页码:197-203 |
| 关键词 | Hydrogenation Platinum Cluster Metal Ion Modifier O-chloronitrobenzene |
| ISSN号 | 0926-860X |
| 英文摘要 | Hydrogenation of o-chloronitrobenzene has been studied in methanol at 303 K and atmospheric pressure over polyvinylpyrrolidone-stabilized platinum colloidal clusters. The catalytic properties of platinum clusters for the hydrogenation of o-chloronitrobenzene to o-chloroaniline were remarkably affected by the metallic cations added. Among these cations, the most favorable influence on activity and selectivity was obtained when Ni2+ ions were used as modifier. The selectivity for o-chloroaniline was increased from 44.7% without a modifier to 66.3% when Ni2+ ions were introduced into the catalyst system, while the activity of the catalyst was nearly doubled by the addition of Ni2+ ion (the average rate of hydrogenation increased from 0.34 mol H-2/mol Pt s on neat platinum cluster to 0.64 mol H-2/mol Pt s on the Pt-Ni2+ system). The highest activity (0.72 mol H-2/mol Pt s) and selectivity (82.9%) to o-chloroaniline was obtained when the molar ratio of Ni2+/Pt was 8. (C) 1997 Elsevier Science B.V. |
| 语种 | 英语 |
| WOS记录号 | WOS:000070990200018 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/74145]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liu, HF |
| 作者单位 | 1.Chinese Acad Sci, Polymer Chem Lab, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Inst Chem, China Petrochem Corp, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, XL,Liu, HF. Influence of metal ions on hydrogenation of o-chloronitrobenzene over platinum colloidal clusters[J]. APPLIED CATALYSIS A-GENERAL,1997,164(1-2):197-203. |
| APA | Yang, XL,&Liu, HF.(1997).Influence of metal ions on hydrogenation of o-chloronitrobenzene over platinum colloidal clusters.APPLIED CATALYSIS A-GENERAL,164(1-2),197-203. |
| MLA | Yang, XL,et al."Influence of metal ions on hydrogenation of o-chloronitrobenzene over platinum colloidal clusters".APPLIED CATALYSIS A-GENERAL 164.1-2(1997):197-203. |
入库方式： OAI收割
来源：化学研究所
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