Effect of morphology on the brittle ductile transition of polymer blends: 6. Influence of rubber particle spatial distribution on the toughening and stiffening efficiency of poly(vinyl chloride) nitrile rubber blends
文献类型:期刊论文
作者 | Liu, ZH; Zhang, XD; Zhu, XG; Qi, ZN; Wang, FS; Li, RKY; Choy, CL |
刊名 | POLYMER
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出版日期 | 1998-10-01 |
卷号 | 39期号:21页码:5047-5052 |
关键词 | Rubber Toughened Poly(Vinyl Chloride) Rubber Particle Spatial Distribution Toughening And Stiffening Efficiency |
ISSN号 | 0032-3861 |
英文摘要 | The influence of rubber particle spatial distribution on the toughening and stiffening efficiency of poly(vinyl chloride) (PVC)/nitrile rubber (NBR) blends is quantitatively studied. Blends with the pseudonetwork morphology or the morphology of well-dispersed rubber particles are used to elucidate the influence. The spatial distribution and matrix ligament thickness considerably affect the impact strengths of PVC/NBR blends. On the other hand, the tensile modulus of the blends is a function of rubber content but not of particle spatial distribution. Quantitative analysis shows that the modulus for the blend with the pseudonetwork morphology is much higher than that for the blend with the morphology of well-dispersed rubber particles for the same values of rubber particle size, size distribution and high impact strength. The dependence of toughening and stiffening efficiency on the spatial distribution is stronger than on the matrix ligament thickness. The pseudonetwork morphology is thus demonstrated to be very efficient in generating PVC/NBR blends simultaneously with high toughness and high stiffness. (C) 1998 Elsevier Science Ltd. All rights reserved. |
语种 | 英语 |
WOS记录号 | WOS:000075216800008 |
出版者 | ELSEVIER SCI LTD |
源URL | [http://ir.iccas.ac.cn/handle/121111/74163] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Qi, ZN |
作者单位 | 1.Chinese Acad Sci, Inst Chem, State Key Lab Engn Plast, Beijing 100080, Peoples R China 2.City Univ Hong Kong, Dept Phys & Mat Sci, Kowloon, Hong Kong 3.Hong Kong Polytech Univ, Dept Appl Phys, Kowloon, Hong Kong |
推荐引用方式 GB/T 7714 | Liu, ZH,Zhang, XD,Zhu, XG,et al. Effect of morphology on the brittle ductile transition of polymer blends: 6. Influence of rubber particle spatial distribution on the toughening and stiffening efficiency of poly(vinyl chloride) nitrile rubber blends[J]. POLYMER,1998,39(21):5047-5052. |
APA | Liu, ZH.,Zhang, XD.,Zhu, XG.,Qi, ZN.,Wang, FS.,...&Choy, CL.(1998).Effect of morphology on the brittle ductile transition of polymer blends: 6. Influence of rubber particle spatial distribution on the toughening and stiffening efficiency of poly(vinyl chloride) nitrile rubber blends.POLYMER,39(21),5047-5052. |
MLA | Liu, ZH,et al."Effect of morphology on the brittle ductile transition of polymer blends: 6. Influence of rubber particle spatial distribution on the toughening and stiffening efficiency of poly(vinyl chloride) nitrile rubber blends".POLYMER 39.21(1998):5047-5052. |
入库方式: OAI收割
来源:化学研究所
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