Synthesis and characterization of water-soluble conducting copolymer poly(aniline-co-o-aminobenzenesulfonic acid)
文献类型：期刊论文
| 作者 | Fan, JH; Wan, MX; Zhu, DB |
| 刊名 | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
 |
| 出版日期 | 1998-12-01 |
| 卷号 | 36期号:17页码:3013-3019 |
| 关键词 | Polyaniline Water Soluble Degree Of Sulfonation Copolymerization |
| ISSN号 | 0887-624X |
| 英文摘要 | The water-soluble conducting copolymer of poly(aniline-co-o-aminobenzenesulfonic acid) (PAOABSA) was synthesized directly from aniline and o-aminobenzenesulfonic acid and characterized by elemental analysis, FTIR, W-Vis, X-ray powder diffraction, and XPS. The room-temperature conductivity of the copolymer can be changed by controlling the molar fraction of the starting materials, and its maximum conductivity at room temperature can reach 3.4 S/cm, which is comparable with polyaniline (PANI) synthesized by the standard method and sulfonated polyaniline (SPAN) having a high degree of sulfonation reported by Wei et al. it was found that the room-temperature conductivity of the copolymer decreases with increase of the degree of sulfonation because of the introduction of the -SO3- group reducing the conjugation of the polymer chain. On the other hand, its solubility in 1.0M NaOH solution increases with increase of the degree of sulfonation due to the -SO3- group linking directly on the phenyl rings of the polymer chain. (C) 1998 John Wiley & Sons, Inc. |
| 语种 | 英语 |
| WOS记录号 | WOS:000077290400002 |
| 出版者 | JOHN WILEY & SONS INC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/74167]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wan, MX |
| 作者单位 | Acad Sinica, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Fan, JH,Wan, MX,Zhu, DB. Synthesis and characterization of water-soluble conducting copolymer poly(aniline-co-o-aminobenzenesulfonic acid)[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,1998,36(17):3013-3019. |
| APA | Fan, JH,Wan, MX,&Zhu, DB.(1998).Synthesis and characterization of water-soluble conducting copolymer poly(aniline-co-o-aminobenzenesulfonic acid).JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,36(17),3013-3019. |
| MLA | Fan, JH,et al."Synthesis and characterization of water-soluble conducting copolymer poly(aniline-co-o-aminobenzenesulfonic acid)".JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 36.17(1998):3013-3019. |
入库方式： OAI收割
来源：化学研究所
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