中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Effect of adsorption on the viscosity of dilute polymer solution

文献类型:期刊论文

作者Cheng, RS; Shao, YF; Liu, MZ; Qian, RY
刊名EUROPEAN POLYMER JOURNAL
出版日期1998-11-01
卷号34期号:11页码:1613-1619
ISSN号0014-3057
英文摘要Measurements of the dilute solution viscosities of polyethylene glycol and polyvinyl alcohol in water were carried out. The reduced viscosities of both polymer solutions show an upward turning of curvature at the extremely dilute concentration region and this is similar to the phenomena observed for many polymer solutions in the early 1950s. Upon the changes of the flow lime of pure water and the wall surface wettability of the viscometer after measuring solution viscosity, a judgement was formed that the observed viscosity abnormality at the extremely dilute concentration region is solely due to the effect of adsorption of polymer chains on the viscometer wall surface. A theory of the adsorption effect based on the Langmuir isotherms was proposed and a mathematical analysis for data treatment was performed. The theory could adequately describe the existing viscosity data. It seems necessary to correct the viscosity of a dilute polymer solution measured by a glass capillary viscometer for effect of adsorption in all cases. (C) 1998 Elsevier Science Ltd. All rights reserved.
语种英语
WOS记录号WOS:000077445300007
出版者PERGAMON-ELSEVIER SCIENCE LTD
源URL[http://ir.iccas.ac.cn/handle/121111/74425]  
专题中国科学院化学研究所
通讯作者Liu, MZ
作者单位1.Nanjing Univ, Dept Chem, Nanjing 210093, Peoples R China
2.Lanzhou Univ, Dept Chem, Lanzhou 730000, Peoples R China
3.Acad Sinica, Inst Chem, Beijing 100080, Peoples R China
推荐引用方式
GB/T 7714
Cheng, RS,Shao, YF,Liu, MZ,et al. Effect of adsorption on the viscosity of dilute polymer solution[J]. EUROPEAN POLYMER JOURNAL,1998,34(11):1613-1619.
APA Cheng, RS,Shao, YF,Liu, MZ,&Qian, RY.(1998).Effect of adsorption on the viscosity of dilute polymer solution.EUROPEAN POLYMER JOURNAL,34(11),1613-1619.
MLA Cheng, RS,et al."Effect of adsorption on the viscosity of dilute polymer solution".EUROPEAN POLYMER JOURNAL 34.11(1998):1613-1619.

入库方式: OAI收割

来源:化学研究所

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