Intramolecular reaction of polymer coordinated cationic rhodium complex
文献类型：期刊论文
| 作者 | Peng, WQ; Zhu, CC; Yuan, GQ |
| 刊名 | SCIENCE IN CHINA SERIES B-CHEMISTRY
 |
| 出版日期 | 1998-02-01 |
| 卷号 | 41期号:1页码:14-20 |
| 关键词 | Complex Square Plane Intramolecular Substitution |
| ISSN号 | 1006-9291 |
| 英文摘要 | A square planar rhodium complex from the copolymer of 2-pyridyl ethylene and other low-molecular weight rhodium complexes with similar structure are reported. The experimental results of XPS and IR spectroscopy indicated that the weak N-->Rh coordination bond can easily replace the strong Rh-C back donation bond with the elevation of temperature due to the steric effect. The terminal carbonyl group in the complex will be substituted to form tridentate and then tetradentate complexes. This is a reversible process. When they are in the atmosphere of CO, tridentate and bidentate complexes will form. These experimental results provide the theoretical reason why the catalytic activities from the polymer coordinated rhodium complex is superior to that of other rhodium complexes. |
| 语种 | 英语 |
| WOS记录号 | WOS:000071615300002 |
| 出版者 | SCIENCE PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/74511]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yuan, GQ |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Peng, WQ,Zhu, CC,Yuan, GQ. Intramolecular reaction of polymer coordinated cationic rhodium complex[J]. SCIENCE IN CHINA SERIES B-CHEMISTRY,1998,41(1):14-20. |
| APA | Peng, WQ,Zhu, CC,&Yuan, GQ.(1998).Intramolecular reaction of polymer coordinated cationic rhodium complex.SCIENCE IN CHINA SERIES B-CHEMISTRY,41(1),14-20. |
| MLA | Peng, WQ,et al."Intramolecular reaction of polymer coordinated cationic rhodium complex".SCIENCE IN CHINA SERIES B-CHEMISTRY 41.1(1998):14-20. |
入库方式： OAI收割
来源：化学研究所
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