New bisdithiolene metal complex of the 2-thioxo-1,3-dithiole-4,5-dithiolato(dmit) ligand. Preparation, structure and physical properties
文献类型：期刊论文
| 作者 | Zhang, QC; Wu, PJ; Sun, SQ; Zhu, DB; Xong, M; Ma, ZS; Shi, NC |
| 刊名 | SYNTHETIC METALS
 |
| 出版日期 | 1998-12-04 |
| 卷号 | 98期号:2页码:103-106 |
| 关键词 | Nickel Complexes Dithiolate Complexes Electrical Conductivity Crystal Structure Synthesis |
| ISSN号 | 0379-6779 |
| 英文摘要 | The complex HMEDA[Ni(dmit)(2)](2)I (HMEDA = Hexamethylethylenediammonium) has been prepared. A single X-ray crystal structure analysis reveals that there are short S ... S contacts between Ni(dmit)(2) dimmers. The monoclinic system, space group p2/n, has cell dimensions: a = 11.710(3) Angstrom, b = 22.559(5) Angstrom, c = 7.374(2) Angstrom, beta = 93.000(3)(0), V = 1945.3(8) Angstrom(3), z = 4. Full-matrix least-squares refinement, based on 2989 reflections converged at R = 0.0686. The conductivity of this salt at room temperature is 0.1 S cm(-1) and it shows semiconducting behavior from 20 to 300 K. (C) 1998 Elsevier Science S.A. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000077636400004 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/74545]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhu, DB |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China 2.China Univ Geosci, Xray Lab, Beijing 100083, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, QC,Wu, PJ,Sun, SQ,et al. New bisdithiolene metal complex of the 2-thioxo-1,3-dithiole-4,5-dithiolato(dmit) ligand. Preparation, structure and physical properties[J]. SYNTHETIC METALS,1998,98(2):103-106. |
| APA | Zhang, QC.,Wu, PJ.,Sun, SQ.,Zhu, DB.,Xong, M.,...&Shi, NC.(1998).New bisdithiolene metal complex of the 2-thioxo-1,3-dithiole-4,5-dithiolato(dmit) ligand. Preparation, structure and physical properties.SYNTHETIC METALS,98(2),103-106. |
| MLA | Zhang, QC,et al."New bisdithiolene metal complex of the 2-thioxo-1,3-dithiole-4,5-dithiolato(dmit) ligand. Preparation, structure and physical properties".SYNTHETIC METALS 98.2(1998):103-106. |
入库方式： OAI收割
来源：化学研究所
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