Phase equilibrium and thermodynamic properties in microemulsions
文献类型：期刊论文
| 作者 | Gu, GX; Wang, WQ; Yan, HK |
| 刊名 | JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
 |
| 出版日期 | 1998 |
| 卷号 | 51期号:1页码:115-123 |
| 关键词 | Calorimetry N-pentanol Phase Equilibrium Sodium Dodecylbenzenesulfonate Thermodynamic Function Water-in-oil Microemulsion |
| ISSN号 | 0368-4466 |
| 英文摘要 | A calorimetric investigation was performed on the partition of n-pentanol in the external oil phase and in the interfacial layer of the water-in-oil microemulsion system sodium dodecyl-benzenesulfonate(DDBS)/n-pentanol/n-heptane/water. The results show that fine changes can be observed in the structure of the water-in-oil emulsion and microemulsion droplets, such as the n-pentanol/DDBS mole ratio increase in the interfacial layer; further, the alcohol/surfactant mole ratio a in the interfacial layer of the droplets, and also the standard thermodynamic functions of the alcohol transition from the external phase to the interfacial phase (Delta G(e-->s)(o), Delta H-c-->s(o) and Delta S-e-->s(o)), can be derived from calorimetric data. |
| 语种 | 英语 |
| WOS记录号 | WOS:000076824800009 |
| 出版者 | KLUWER ACADEMIC PUBL |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/74555]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, WQ |
| 作者单位 | 1.Beijing Univ, Dept Tech Phys, Beijing 100871, Peoples R China 2.Natl Inst Metrol, Energy Conservat Div, Beijing 100013, Peoples R China 3.Acad Sinica, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gu, GX,Wang, WQ,Yan, HK. Phase equilibrium and thermodynamic properties in microemulsions[J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,1998,51(1):115-123. |
| APA | Gu, GX,Wang, WQ,&Yan, HK.(1998).Phase equilibrium and thermodynamic properties in microemulsions.JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,51(1),115-123. |
| MLA | Gu, GX,et al."Phase equilibrium and thermodynamic properties in microemulsions".JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY 51.1(1998):115-123. |
入库方式： OAI收割
来源：化学研究所
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