Vibrational energy transfer from highly excited state CO to C2H2
文献类型：期刊论文
| 作者 | Wang, BS; Guo, JZ; Gu, YS |
| 刊名 | ACTA PHYSICO-CHIMICA SINICA
 |
| 出版日期 | 1998-04-01 |
| 卷号 | 14期号:4页码:327-331 |
| 关键词 | Time-resolved Ir Spectra Highly Vibrational Excited State V-v Energy Transfer |
| ISSN号 | 1000-6818 |
| DOI | 10.3866/PKU.WHXB19980408 |
| 英文摘要 | The energy transfer process of highly vibrational states of CO with C2H2 has been studied by the Time-resolved Fourier Transform Infrared Emission Spectroscopy. The vibrational population of CO (upsilon=1-3) were obtained by the simulations of the IR emission spectra. Differentiation method was used to calculate the quenching rate constants of CO(upsilon=1-3) which are 2.0+/-0.1, 6.0+/-0.2 and 9.4+/-0.8 (10(-13) cm(3).molecule(-1).S-1), respectively. The west possible energy transfer channel is the transfer of CO(upsilon) to C2H2 (upsilon(2)). Dimer complexes may be formed in the collisional process. The equilibrium structures and lifetime of the complexes were estimated by ab initio computation and V-V/R theory. |
| 语种 | 英语 |
| WOS记录号 | WOS:000074858600008 |
| 出版者 | PEKING UNIV PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/74597]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Gu, YS |
| 作者单位 | 1.Shandong Univ, Dept Chem, Jinan 250100, Peoples R China 2.Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, BS,Guo, JZ,Gu, YS. Vibrational energy transfer from highly excited state CO to C2H2[J]. ACTA PHYSICO-CHIMICA SINICA,1998,14(4):327-331. |
| APA | Wang, BS,Guo, JZ,&Gu, YS.(1998).Vibrational energy transfer from highly excited state CO to C2H2.ACTA PHYSICO-CHIMICA SINICA,14(4),327-331. |
| MLA | Wang, BS,et al."Vibrational energy transfer from highly excited state CO to C2H2".ACTA PHYSICO-CHIMICA SINICA 14.4(1998):327-331. |
入库方式： OAI收割
来源：化学研究所
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