Voltammograms of thin layer Pd vertical bar H(D) electrodes in the coexistence of alpha and beta phases
文献类型：期刊论文
| 作者 | Zhang, WS; Zhang, XW; Zhao, XG |
| 刊名 | JOURNAL OF ELECTROANALYTICAL CHEMISTRY
 |
| 出版日期 | 1998-10-30 |
| 卷号 | 458期号:1-2页码:107-112 |
| 关键词 | Phase Transition Cyclic Voltammetry Pd Vertical Bar h Electrode Pd Vertical Bar h System Kinetics |
| ISSN号 | 0022-0728 |
| 英文摘要 | The kinetics of a thin layer Pd \ H(D) electrode at the coexistence of alpha and beta phases in cyclic voltammetry are studied and the effects of various parameters are discussed. It is found that the voltammogram of the alpha<->beta phase transition is trigonal in shape which differs significantly from those for diffusion and adsorption. The kinetic characteristics of the alpha+beta mixed region are controlled by the deviation of parameters from the thermodynamic values. These results indicate that cyclic voltammetry can be used for studying the kinetics of phase transition occurring in a layer electrode. The present treatment is verified by comparison with the previous experimental results. (C) 1998 Elsevier Science S.A. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000077470400011 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/74627]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang, WS |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China 2.Inst Appl Phys & Computat Math, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, WS,Zhang, XW,Zhao, XG. Voltammograms of thin layer Pd vertical bar H(D) electrodes in the coexistence of alpha and beta phases[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY,1998,458(1-2):107-112. |
| APA | Zhang, WS,Zhang, XW,&Zhao, XG.(1998).Voltammograms of thin layer Pd vertical bar H(D) electrodes in the coexistence of alpha and beta phases.JOURNAL OF ELECTROANALYTICAL CHEMISTRY,458(1-2),107-112. |
| MLA | Zhang, WS,et al."Voltammograms of thin layer Pd vertical bar H(D) electrodes in the coexistence of alpha and beta phases".JOURNAL OF ELECTROANALYTICAL CHEMISTRY 458.1-2(1998):107-112. |
入库方式： OAI收割
来源：化学研究所
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