Synthesis, electrical properties of [Ni(dmit)(2)](-) complexes and X-ray crystal structure of [EDA][Ni(dmit)(2)] (dmit equals 1,3-dithiol-2-thione-4,5-dithiolate)
文献类型：期刊论文
| 作者 | Sun, SQ; Wu, PJ; Zhu, DB; Ma, ZS; Shi, NC |
| 刊名 | INORGANICA CHIMICA ACTA
 |
| 出版日期 | 1998-02-03 |
| 卷号 | 268期号:1页码:103-107 |
| 关键词 | Nickel Complexes Dithiolate Complexes Electrical Conductivity Crystal Structures Synthesis |
| ISSN号 | 0020-1693 |
| 英文摘要 | The complexes [MDC] [Ni(dmit)(2)] (1) (MDC = dimethylamino-dithioImethyl carbonium), [MDA] [Ni(dmit)(2)] (2) (MDA = 2-dimethylamino-1,3-dithiolanylium), [PDA] [Ni(dmit)(2)] (3) (PDA = 2-cyclopentaamino-1,3-dithiolanylium) and [EDA] [Ni(dmit)(2)] (4) (EDA = 2-diethylamino-1,3-dithiolanylium) have been prepared. All these complexes behave as semiconductors. However, the conductivities increased by 10(3)-10(5) times when they were doped with iodine. A single X-ray crystal structure analysis of complex 3 reveals that there are short S ... S contacts between cation and anion complexes. The triclinic system, space group P (1) over bar, has cell dimensions a = 10.113(3), b = 13.612(4), c = 9.151(3) Angstrom, alpha = 69.57(3), beta = 77.22(3), gamma = 82.54(3)degrees and Z = 2. Full-matrix least-squares refinement, based on 2801 reflections converged at R = 0.062. (C) 1998 Elsevier Science S.A. |
| 语种 | 英语 |
| WOS记录号 | WOS:000071095000014 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/74707]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhu, DB |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China 2.China Univ Geosci, Xray Lab, Beijing 100083, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sun, SQ,Wu, PJ,Zhu, DB,et al. Synthesis, electrical properties of [Ni(dmit)(2)](-) complexes and X-ray crystal structure of [EDA][Ni(dmit)(2)] (dmit equals 1,3-dithiol-2-thione-4,5-dithiolate)[J]. INORGANICA CHIMICA ACTA,1998,268(1):103-107. |
| APA | Sun, SQ,Wu, PJ,Zhu, DB,Ma, ZS,&Shi, NC.(1998).Synthesis, electrical properties of [Ni(dmit)(2)](-) complexes and X-ray crystal structure of [EDA][Ni(dmit)(2)] (dmit equals 1,3-dithiol-2-thione-4,5-dithiolate).INORGANICA CHIMICA ACTA,268(1),103-107. |
| MLA | Sun, SQ,et al."Synthesis, electrical properties of [Ni(dmit)(2)](-) complexes and X-ray crystal structure of [EDA][Ni(dmit)(2)] (dmit equals 1,3-dithiol-2-thione-4,5-dithiolate)".INORGANICA CHIMICA ACTA 268.1(1998):103-107. |
入库方式： OAI收割
来源：化学研究所
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