Influence of interfacial adhesion on toughening of polyethylene-octene elastomer nylon 6 blends
文献类型:期刊论文
作者 | Yu, ZZ; Ou, YC; Hu, GH |
刊名 | JOURNAL OF APPLIED POLYMER SCIENCE
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出版日期 | 1998-08-29 |
卷号 | 69期号:9页码:1711-1718 |
关键词 | Super-tough Nylon 6 Elastomer Toughening Interfacial Modifier Compatibilization |
ISSN号 | 0021-8995 |
英文摘要 | Super-tough nylon 6 was prepared by using polyethylene-octene elastomer (POE) grafted with maleic anhydride as a toughener. The influences of maleating and a compatibilizer on interfacial adhesion and mechanical properties of nylon 6/POE blends were investigated in terms of mechanical testing, Molau tests, SEM observations, IR analyses, and rheological behavior. The results show that the unmodified POE has hardly any contribution to toughness of nylon 6, whereas the maleic anhydride-grafted POE (POE-g-MA) significantly improves the compatibility of POE with nylon 6 and sharply reduces its size in the nylon 6 matrix due to the in situ formation of a graft copolymer between POE-g-MA and nylon 6 during melt processing. With the POE-g-MA, a transition from brittle to ductile occurs. Besides, the use of a compatibilizer in nylon G/POE-g-MA system shifts the brittle-ductile transition curve to a lower POE-g-MA content, which is attributed, in part, to the chain-extending effect of CE-96 on the nylon 6 matrix leading to further reduction of the sizes of POE-g-MA in the matrix, in part, to the coupling reaction of CE-96 between POE-g-MA and nylon 6. (C) 1998 John Wiley & Sons, Inc. J Appl Polym Sci 69: 1711-1718, 1998. |
语种 | 英语 |
WOS记录号 | WOS:000075124200004 |
出版者 | JOHN WILEY & SONS INC |
源URL | [http://ir.iccas.ac.cn/handle/121111/74725] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Ou, YC |
作者单位 | 1.Chinese Acad Sci, Inst Chem, State Key Lab Engn Plast, Beijing 100080, Peoples R China 2.ECPM, Dept Polymeres, Lab Extrus React, F-67000 Strasbourg, France |
推荐引用方式 GB/T 7714 | Yu, ZZ,Ou, YC,Hu, GH. Influence of interfacial adhesion on toughening of polyethylene-octene elastomer nylon 6 blends[J]. JOURNAL OF APPLIED POLYMER SCIENCE,1998,69(9):1711-1718. |
APA | Yu, ZZ,Ou, YC,&Hu, GH.(1998).Influence of interfacial adhesion on toughening of polyethylene-octene elastomer nylon 6 blends.JOURNAL OF APPLIED POLYMER SCIENCE,69(9),1711-1718. |
MLA | Yu, ZZ,et al."Influence of interfacial adhesion on toughening of polyethylene-octene elastomer nylon 6 blends".JOURNAL OF APPLIED POLYMER SCIENCE 69.9(1998):1711-1718. |
入库方式: OAI收割
来源:化学研究所
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