Chiral dendrimers with axial chirality
文献类型：期刊论文
| 作者 | Chen, YM; Chen, CF; Xi, F |
| 刊名 | CHIRALITY
 |
| 出版日期 | 1998 |
| 卷号 | 10期号:7页码:661-666 |
| 关键词 | Chiral Dendrimers Dendrimers Axial Chirality Optical Rotation Circular Dichroism (r)-(+)-1 1 '-bi-2 2 '-naphthol |
| ISSN号 | 0899-0042 |
| 英文摘要 | The synthesis and optical activity of novel chiral dendrimers with axial chirality are reported. The dendrimers were constructed by coupling of the polyether dendritic bromides with (R)-(+)-1,1'-bi-2-naphthol (1), The uniform (2, 3, 4) and nonuniform double-O-alkylated (8, 9, 10) as well as mono-O-alkylated (5, 6, 7) products were thus obtained. These chiral molecules were characterized by H-1- and C-13-NMR, elemental analysis, optical rotation, adsorption spectra, and circular dichroism. It was found that the specific rotation decreases with the increase of the number of generation for each group of dendrimers (2-4, 5-7, and 8-10, respectively). In terms of the molar rotation, it was quite different; the molar rotation increased sharply for dendrimers, 2-4, but only slightly for dendrimers 5-7, The dihedral angle change of bi-naphthyl in the synthesized dendrimers was discussed based on the CD spectra. (C) 1998 Wiley-Liss, Inc. |
| 语种 | 英语 |
| WOS记录号 | WOS:000076046800011 |
| 出版者 | WILEY-LISS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/74737]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Chen, YM |
| 作者单位 | Chinese Acad Sci, Polymer Chem Lab, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, YM,Chen, CF,Xi, F. Chiral dendrimers with axial chirality[J]. CHIRALITY,1998,10(7):661-666. |
| APA | Chen, YM,Chen, CF,&Xi, F.(1998).Chiral dendrimers with axial chirality.CHIRALITY,10(7),661-666. |
| MLA | Chen, YM,et al."Chiral dendrimers with axial chirality".CHIRALITY 10.7(1998):661-666. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。