A model for correlating the solubility of solids in supercritical CO2
文献类型：期刊论文
| 作者 | Zhong, MH; Han, BX; Ke, J; Yan, HK; Peng, DY |
| 刊名 | FLUID PHASE EQUILIBRIA
 |
| 出版日期 | 1998-05-01 |
| 卷号 | 146期号:1-2页码:93-102 |
| 关键词 | Supercritical Fluid Solid-fluid Equilibria Cluster |
| ISSN号 | 0378-3812 |
| 英文摘要 | A model for correlating the phase equilibria of solid-supercritical fluid (SCF) systems has been developed. The model is based on the fact that the free solute molecules, the solvent molecules, and the solute-solvent clusters in such a solid-SCF system are in chemical equilibrium. The local density of the solvent surrounding a solute is used as one of the parameters in the model. The validity of the model is verified by correlation of the phase equilibrium data of supercritical CO2-solid systems reported in the literature. Using the solubility data, the model can be used to estimate the local density and the average number of the solvent molecules in the clusters. (C) 1998 Elsevier Science B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000074478100008 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/74801]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Han, BX |
| 作者单位 | 1.Acad Sinica, Inst Chem, Beijing 100080, Peoples R China 2.Univ Saskatchewan, Dept Chem Engn, Saskatoon, SK S7N 5C9, Canada |
| 推荐引用方式 GB/T 7714 | Zhong, MH,Han, BX,Ke, J,et al. A model for correlating the solubility of solids in supercritical CO2[J]. FLUID PHASE EQUILIBRIA,1998,146(1-2):93-102. |
| APA | Zhong, MH,Han, BX,Ke, J,Yan, HK,&Peng, DY.(1998).A model for correlating the solubility of solids in supercritical CO2.FLUID PHASE EQUILIBRIA,146(1-2),93-102. |
| MLA | Zhong, MH,et al."A model for correlating the solubility of solids in supercritical CO2".FLUID PHASE EQUILIBRIA 146.1-2(1998):93-102. |
入库方式： OAI收割
来源：化学研究所
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