Catalytic behavior of a Wool-Pd complex in asymmetric hydrogenation of diacetone alcohol and 3-methyl-2-butanone
文献类型：期刊论文
| 作者 | Yin, MY; Yuan, GL; Huang, MY; Jiang, YY |
| 刊名 | JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
 |
| 出版日期 | 1999-11-17 |
| 卷号 | 147期号:1-2页码:89-92 |
| 关键词 | Wool-pd Complex Diacetone Alcohol Asymmetric Hydrogenation |
| ISSN号 | 1381-1169 |
| 英文摘要 | A Wool-Pd complex has been found to be able to catalyze the asymmetric hydrogenation of diacetone alcohol to (R)-2-methyl-2,4-pentanediol acid 3-methyl-2-butanone to (R)-3-methyl-2-butanol at 30 degrees C and under 1 atm H-2. The optical yields were greatly affected by Pd content in Wool-Pd complex. When a proper Pd content was selected, (R)-2-methyl-2,4-pentanediol and (R)-3-methyl-2-butanol could be obtained in 73 and 100% optical yield, respectively. This chiral natural biopolymer-Pd complex catalyst was easy to prepare and could be reused without appreciable change in optical catalytic activity. (C) 1999 Elsevier Science B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000083978400013 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/74815]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yuan, GL |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yin, MY,Yuan, GL,Huang, MY,et al. Catalytic behavior of a Wool-Pd complex in asymmetric hydrogenation of diacetone alcohol and 3-methyl-2-butanone[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,1999,147(1-2):89-92. |
| APA | Yin, MY,Yuan, GL,Huang, MY,&Jiang, YY.(1999).Catalytic behavior of a Wool-Pd complex in asymmetric hydrogenation of diacetone alcohol and 3-methyl-2-butanone.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,147(1-2),89-92. |
| MLA | Yin, MY,et al."Catalytic behavior of a Wool-Pd complex in asymmetric hydrogenation of diacetone alcohol and 3-methyl-2-butanone".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 147.1-2(1999):89-92. |
入库方式： OAI收割
来源：化学研究所
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