Nickel-catalyzed carbonylation of methyl acetate to acetic anhydride
文献类型：期刊论文
| 作者 | Gong, JF; Fan, QH; Jiang, DZ |
| 刊名 | JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
 |
| 出版日期 | 1999-11-17 |
| 卷号 | 147期号:1-2页码:113-124 |
| 关键词 | Nickel Catalyst Carbonylation Acetic Anhydride Ligand Mechanism |
| ISSN号 | 1381-1169 |
| 英文摘要 | Liquid phase carbonylation of methyl acetate to acetic anhydride using nickel catalyst with methyl iodide promoter is reported. Effect of different catalyst precursors, total reaction pressure, hydrogen partial pressure, temperature, catalyst, lithium acetate and methyl iodide concentration, a variety of ligands on the activity and selectivity of nickel catalyst has been investigated. Additionally, FT-IR spectra of the reaction solution were studied and possible side reactions in the carbonylation were examined. Based on these observations, a proposed mechanism for the homogeneous nickel-catalyzed carbonylation of methyl acetate was discussed. (C) 1999 Elsevier Science B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000083978400017 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/74847]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Jiang, DZ |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gong, JF,Fan, QH,Jiang, DZ. Nickel-catalyzed carbonylation of methyl acetate to acetic anhydride[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,1999,147(1-2):113-124. |
| APA | Gong, JF,Fan, QH,&Jiang, DZ.(1999).Nickel-catalyzed carbonylation of methyl acetate to acetic anhydride.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,147(1-2),113-124. |
| MLA | Gong, JF,et al."Nickel-catalyzed carbonylation of methyl acetate to acetic anhydride".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 147.1-2(1999):113-124. |
入库方式： OAI收割
来源：化学研究所
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