Enantioselective hydrogenation of methyl pyruvate over polymer-stabilized and supported iridium clusters
文献类型：期刊论文
| 作者 | Zuo, XB; Liu, HF; Yue, C |
| 刊名 | JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
 |
| 出版日期 | 1999-11-17 |
| 卷号 | 147期号:1-2页码:63-72 |
| 关键词 | Iridium Methyl Pyruvate Cinchonidine Enantioselective Hydrogenation Rate-promoting Effect |
| ISSN号 | 1381-1169 |
| 英文摘要 | The enantioselective hydrogenation of methyl pyruvate was studied over finely dispersed polyvinylpyrrolidone-stabilized iridium (PVP-Ir) and the corresponding alumina-supported iridium cluster (Al2O3-Ir) modified with cinchonidine. It was found that the modifier, apart from inducing enantioselectivity, has a considerable rate-promoting effect on this reaction with the average rate increased by a actor of 2-3.5 over both the two kinds of catalysts. Favorable reaction parameters were 283 K, 4.0 MPa and alcohols or acetic acid as solvents. Similar to what had been reported in Pt/cinchona system, the highest value of the enantiomeric excess (34.1%) was obtained in acetic acid, accompanied by a marked enhancement of the reaction rate. (C) 1999 Elsevier Science B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000083978400010 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/74871]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liu, HF |
| 作者单位 | 1.Chinese Acad Sci, Polymer Chem Lab, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Inst Chem, China PetroChem Corp, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zuo, XB,Liu, HF,Yue, C. Enantioselective hydrogenation of methyl pyruvate over polymer-stabilized and supported iridium clusters[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,1999,147(1-2):63-72. |
| APA | Zuo, XB,Liu, HF,&Yue, C.(1999).Enantioselective hydrogenation of methyl pyruvate over polymer-stabilized and supported iridium clusters.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,147(1-2),63-72. |
| MLA | Zuo, XB,et al."Enantioselective hydrogenation of methyl pyruvate over polymer-stabilized and supported iridium clusters".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 147.1-2(1999):63-72. |
入库方式： OAI收割
来源：化学研究所
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