Hydrogenation of aldehydes and ketones catalyzed by zeolite-supported polyvinyl alcohol amino acid platinum complex
文献类型：期刊论文
| 作者 | Liu, L; Xia, D; Zhang, Q; Huang, MY; Jiang, YY |
| 刊名 | POLYMERS FOR ADVANCED TECHNOLOGIES
 |
| 出版日期 | 1999 |
| 卷号 | 10期号:1-2页码:103-107 |
| 关键词 | Hydrogenation Aldehyde And Ketone Polyvinyl Alcohol Amino Acid Platinum Complex |
| ISSN号 | 1042-7147 |
| 英文摘要 | Zeolite-supported polyvinyl alcohol-amino acid (alanine, proline, glutamine, leucine or lysine)-platinum complexes (Zeo-PVA-AA-Pt) have been prepared by a very simple method and have been found to catalyze the hydrogenation of some aldehydes and ketones such as hexanal, benzaldehyde, cyclohexanone, 2-pentanone, methyl acetoacetate, ethyl acetoacetate, 2,4-pentandione to 1-hexanol, cyclohexylmethanol, cyclohexanol, 2-pentanol, methyl 3-hydroxybutyrate, ethyl 3-hydroxybutyrate and 2,4-pentandiol, respectively, at 55 degrees C and under an atmospheric hydrogen pressure. In several cases, the yield or selectivity amounted to 100%. Such catalysts were very stable in the hydrogenation, and could be reused several times without any remarkable change in the catalytic activity. The catalytic activity was greatly affected by molar ratios of monomer unit of polyvinyl alcohol to amino acid, amino acid to Pt in the complex, and the nature of the amino acids and solvent used in hydrogenation. |
| 语种 | 英语 |
| WOS记录号 | WOS:000078515800020 |
| 出版者 | JOHN WILEY & SONS LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/74895]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liu, L |
| 作者单位 | 1.Acad Sinica, Grad Sch, Dept Chem, Beijing 100039, Peoples R China 2.Acad Sinica, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, L,Xia, D,Zhang, Q,et al. Hydrogenation of aldehydes and ketones catalyzed by zeolite-supported polyvinyl alcohol amino acid platinum complex[J]. POLYMERS FOR ADVANCED TECHNOLOGIES,1999,10(1-2):103-107. |
| APA | Liu, L,Xia, D,Zhang, Q,Huang, MY,&Jiang, YY.(1999).Hydrogenation of aldehydes and ketones catalyzed by zeolite-supported polyvinyl alcohol amino acid platinum complex.POLYMERS FOR ADVANCED TECHNOLOGIES,10(1-2),103-107. |
| MLA | Liu, L,et al."Hydrogenation of aldehydes and ketones catalyzed by zeolite-supported polyvinyl alcohol amino acid platinum complex".POLYMERS FOR ADVANCED TECHNOLOGIES 10.1-2(1999):103-107. |
入库方式： OAI收割
来源：化学研究所
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